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Moreau, M.; Daughney, C. |
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Title |
Defining natural baselines for rates of change in New Zealand’s groundwater quality: Dealing with incomplete or disparate datasets, accounting for impacted sites, and merging into state of the-environment reporting |
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Journal Article |
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Year |
2021 |
Publication |
Science of The Total Environment |
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755 |
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143292 |
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Baseline, Groundwater quality, Machine-learning, Monitoring, New Zealand, Trends |
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To effectively manage sustainably groundwater bodies, it is essential to establish what the naturally occurring ranges of chemical concentrations in groundwaters are and how they change over time. We defined baseline trends for New Zealand groundwaters using: 1) pattern recognition techniques to deal with inconsistent monitoring suites between the national (110 sites) and the denser regional network (\textgreater1000 sites), and 2) multivariate statistics to identify and remove impacted sites from the enhanced dataset. Rates of changes were calculated for 13 parameters between January 2005 and December 2014 at more than 1000 groundwater quality monitoring sites. The resulting dataset included 262 complete cases (CC), which was enhanced using Machine-Learning (ML) techniques to a total of 607 sites. Hierarchical cluster analysis was used to identify trend clusters that were consistent between the CC, ML-enhanced datasets and a 2006 study based on solely on the national network. The largest cluster (WR) consisted of low magnitude changes across all parameters and was attributed to water-rock interaction processes. The second largest cluster (I) exhibited fast changes particularly for parameters linked to human-induced impact. The third largest cluster (D) comprised decreases of all parameters and was associated with dilution processes. Trend clusters were further refined using groundwater quality state information, enabling the identification of impacted sites outside of Cluster I in the ML-enhanced and CC datasets. Corresponding trend baselines were subsequently derived at unimpacted sites using univariate quantile distribution (5th and 95th percentile thresholds). Finally, we developed classifications combining baselines (state and trend) and natural variability to enhance state of the environment reporting. This allowed the new identification of deteriorating trends at sites where groundwater quality state is not yet affected in addition to trend reversals. These classifications can be adapted to incorporate new knowledge or align with surface water quality reporting. |
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0048-9697 |
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THL @ christoph.kuells @ moreau_defining_2021 |
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164 |
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Mühr-Ebert, E.L.; Wagner, F.; Walther, C. |
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Title |
Speciation of uranium: Compilation of a thermodynamic database and its experimental evaluation using different analytical techniques |
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Journal Article |
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Year |
2019 |
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Applied Geochemistry |
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100 |
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213-222 |
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Environmental hazards are caused by uranium mining legacies and enhanced radioactivity in utilized groundwater and surface water resources. Knowledge of uranium speciation in these waters is essential for predicting radionuclide migration and for installing effective water purification technology. The validity of the thermodynamic data for the environmental media affected by uranium mining legacies is of utmost importance. Therefore, a comprehensive and consistent database was established according to current knowledge. The uranium data included in the database is based on the NEA TDB (Guillaumont et al., 2003) and is modified or supplemented as necessary e.g. for calcium and magnesium uranyl carbonates. The specific ion interaction theory (Brönsted, 1922) is used to estimate activity constants, which is sufficient for the considered low ionic strengths. The success of this approach was evaluated by comparative experimental investigations and model calculations (PHREEQC (Parkhurst and Appelo, 1999)) for several model systems. The waters differ in pH (2.7–9.8), uranium concentration (10−9-10−4 mol/L) and ionic strength (0.002–0.2 mol/L). We used chemical extraction experiments, ESI-Orbitrap-MS and time-resolved laser-induced fluorescence spectroscopy (TRLFS) to measure the uranium speciation. The latter method is nonintrusive and therefore does not change the chemical composition of the investigated waters. This is very important, because any change of the system under study may also change the speciation. |
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0883-2927 |
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THL @ christoph.kuells @ muhr-ebert_speciation_2019 |
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142 |
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Musy, S.; Meyzonnat, G.; Barbecot, F.; Hunkeler, D.; Sültenfuss, J.; Solomon, D.K.; Purtschert, R. |
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In-situ sampling for krypton-85 groundwater dating |
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Journal Article |
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2021 |
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Journal of Hydrology X |
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11 |
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100075 |
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Noble gases, Tracers, Groundwater, Dating, Sampling Methodology |
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Krypton-85 and other radioactive noble gases are widely used for groundwater dating purposes. 85Kr analysis require large volumes of water to reach the analytical requirements. Conventionally, this water is pumped to the surface to be degassed with a gas extraction system. The large pumping rate may disturb the natural flow field and requires substantial field logistics. Hence, we propose a new in-situ degassing method, in which membrane contactors are used to degas the groundwater directly in the well and gas is collected at the surface. This way, field work is facilitated, groundwater system disturbance is minimized, and the gas sample is collected at a specific depth. We demonstrate the tightness of the system regarding atmospheric air contamination for a collection times of 24 h, which is sufficient for both low-level counting and laser-based counting methods for 85Kr. The minimal borehole diameter is 7.5 cm for the prototype presented in this research but can easily be reduced to smaller diameters. In a case study, we compare the results obtained with the new passive method with those from a conventional packer setup sampling. Additionally, 3H/3He samples were collected for both sampling regimes and the dating results were compared with those from 85Kr. A good agreement between tracer ages is demonstrated and the age stratigraphy is consistent with the expected age distribution for a porous unconfined aquifer. In addition, our study emphasizes the differences between the age information sampled with various methods. In conclusion, we demonstrate that the new in situ quasi-passive method provides a more representative age stratigraphy with depth in most cases. |
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2589-9155 |
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THL @ christoph.kuells @ Musy2021100075 |
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215 |
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Musy, S.; Purtschert, R. |
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Title |
Reviewing 39Ar and 37Ar underground production in shallow depths with implications for groundwater dating |
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Journal Article |
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Year |
2023 |
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Science of The Total Environment |
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884 |
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163868 |
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Subsurface production, Argon-39, Argon-37, Muons, Isotope hydrology, Tracers |
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Argon-37 (37Ar) and Argon-39 (39Ar) are used for groundwater dating on timescales from weeks to centuries. For both isotopes, the quantification of underground sources is essential to accurately infer water residence times from sampled dissolved activities. Subsurface production resulting from interactions with neutrons from the natural radioactivity in rocks and with primary cosmogenic neutrons has been known for a long time. More recently, the capture of slow negative muons and reactions with muon-induced neutrons were documented for 39Ar subsurface production in the context of underground particle detectors (e.g. for Dark Matter research). However, the contribution from these particles was never considered for groundwater dating applications. Here, we reevaluate the importance of all potential depth-related production channels at depth ranges relevant for 39Ar groundwater dating [0 − 200 meters below the surface (m.b.s)]. The production of radioargon by muon-induced processes is considered in this depth range for the first time. The uncertainty on the total depth-dependent production rate is estimated with Monte Carlo simulations assuming a uniform distribution of the parameter uncertainties. This work aims to provide a comprehensive framework for interpreting 39Ar activities in terms of groundwater residence times and for exposure age dating of rocks. The production of 37Ar is also addressed since this isotope is relevant as a proxy for 39Ar production, for the timing of river-groundwater exchanges, and in the context of on-site inspections (OSI) within the verification framework of the Comprehensive Nuclear-Test-Ban Treaty (CTBT). In this perspective, we provide an interactive web-based application for the calculation of 37Ar and 39Ar production rates in rocks. |
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0048-9697 |
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THL @ christoph.kuells @ Musy2023163868 |
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217 |
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N, D.; Panda, B.; S, C.; V, P.M.; Singh, D.K.; L, R.A.; Sahoo, S.K. |
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Spatio-temporal variations of Uranium in groundwater: Implication to the environment and human health |
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Journal Article |
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Year |
2021 |
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Science of The Total Environment |
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775 |
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145787 |
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Groundwater, Health risk, Speciation, Stable isotopes, Statistics, Uranium |
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Groundwater overexploitation has resulted in huge scarcity and increase in the demand for water and food security in India. Groundwater in India has been observed to have experienced various water quality issues like arsenic, fluoride, and Uranium (U) contamination, leading to risk in human health. Markedly, the health risk of higher U in drinking water, as well as its chemical toxicity in groundwater have adverse effects on human. This study has reported occurrence of U as an emerging and widespread phenomenon in South Indian groundwater. Data on U in groundwater were generated from 284 samples along the Cretaceous Tertiary boundary within 4 seasons viz. pre-monsoon (PRM), southwest monsoon (SWM), northeast monsoon (NEM), and post-monsoon (POM). High U concentrations (74 μgL−1) showed to be above the World Health Organization’s provisional guideline value of 30 μgL−1. The geochemical, stable isotope and geophysical studies suggested that U in groundwater could vary with respect to season and was noted to be highest during NEM. The bicarbonate (HCO3) released by weathering process during monsoon could affect the saturation index (SI)Calcite and carbonate species of U. However, the primary source of U was found to be due to geogenic factors, like weathering, dissolution, and groundwater level fluctuation, and that, U mobilization could be enhanced due to anthropogenic activities. The findings further indicated that groundwater in the study area has reached the alarming stage of chemical toxicity. Hence, it is urgent and imperative that workable management strategies for sustainable drinking water source be developed and preventive measures be undertaken, relative to these water quality concerns to mitigate their disconcerting effect on human health. |
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0048-9697 |
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THL @ christoph.kuells @ n_spatio-temporal_2021 |
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146 |
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Naghedifar, S.M.; Ziaei, A.N.; Naghedifar, S.A.; Ansari, H. |
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A new model for simulation of collection and conveyance sections of Qanat |
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2020 |
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Journal of Hydrology |
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590 |
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125218 |
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Richards’ equation, Saint-Venant equation, Numerical modeling, Qanat-aquifer system |
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In this paper, a new numerical model has been developed for simulation of Qanat-aquifer system. This model employs quasi-3D mixed-form of Richards’ equation and 1D fully-hydrodynamic form of Saint-Venant equations to simulate subsurface and overland flow, respectively. In order to handle non-orthogonal grids, subsurface flow module benefits from coordinate transformation technique. Using the above-mentioned governing equations, the presented model is able to simulate water flow inside both collection and conveyance sections of the gallery as well as dynamics of groundwater and vadose zone from impermeable bed rock to the soil-air interface. Since measured data corresponding to the hydraulics of Qanats is scarce, the overland and subsurface modules have been validated with analytical, numerical and experimental benchmarks in the literature. Subsequently, the model was employed to simulate ten different hypothetical aquifer-Qanat systems with different properties including the depth of groundwater aquifer, roughness of the gallery and saturated hydraulic conductivity of the gallery-aquifer boundary and the influence of each the parameters was monitored on the outflow rate at the appearance point of each Qanat. Furthermore, the advance of water inside two initially dry galleries were simulated at different time levels up to steady state. Eventually, the streamlines have been shown at the steady state for two Qanat-aquifer systems. Although, the presented study sheds light on some aspects of Qanat-aquifer hydraulics, the validation of the presented model with in-lab or on-field data remains ongoing for the future researches. |
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0022-1694 |
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THL @ christoph.kuells @ Naghedifar2020125218 |
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254 |
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Netzer, L.; Kurtzman, D.; Ben-Hur, M.; Livshitz, Y.; Katzir, R.; Nachshon, U. |
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Novel approach to roof rainwater harvesting and aquifer recharge in an urban environment: Dry and wet infiltration wells comparison |
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2024 |
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Water Research |
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252 |
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121183 |
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Rainwater harvesting, Managed aquifer recharge, Urban hydrology, Infiltration wells |
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In urban environments there is a severe reduction of infiltration and groundwater recharge due to the existence of large impervious areas. During rain events, large volumes of water that could have recharged groundwater and surface water bodies are diverted into the municipal drainage system and lost from the freshwater storage. Moreover, extreme rain events impose high peak flows and large runoff volumes, which increase the risk of urban floods. Recent studies have suggested the use of rainwater harvesting for groundwater recharge, as a plausible solution for these challenges in dense urban environments. While the benefits of this approach are well understood, research on its practical, engineering, and hydrological aspects is relatively limited. The objective of the present study was to examine the use of infiltration wells for groundwater recharge with harvested rainwater collected from building rooftops under Mediterranean climate conditions. Two types of wells with similar hydraulic and technical properties were examined: a well that reaches the groundwater (wet well); and a well that discharges the harvested water into the unsaturated zone (dry well). Infiltration capacities of the wells were compared in controlled experiments conducted during summer months, and in operational recharge of harvested rainwater, during winter. Both dry and wet wells were found to be suitable for purposes of groundwater recharge with rooftop-harvested rainwater. Infiltration capacity of the wet well was about seven times greater than the infiltration capacity of the dry well. While the infiltration capacity of the wet well was constant throughout the entire length of the study (∼10 m3/h/m), the dry well infiltration capacity improved during winter (from 0.5 m3/h/m to 1.5 m3/h/m), a result of development of the dry well with time. Considering Tel-Aviv, Israel, as a case study for a dense modern city in a Mediterranean climate, it is demonstrated herein that the use of infiltration wells may reduce urban drainage by ∼40 %. |
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0043-1354 |
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THL @ christoph.kuells @ Netzer2024121183 |
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230 |
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Nijsten, G.-J.; Christelis, G.; Villholth, K.G.; Braune, E.; Gaye, C.B. |
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Transboundary aquifers of Africa: Review of the current state of knowledge and progress towards sustainable development and management |
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2018 |
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Journal of Hydrology: Regional Studies |
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20 |
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21-34 |
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Africa, Assessment, Governance, Indicators, Transboundary aquifers |
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Study region Transboundary aquifers (TBAs) of Africa. Study focus Review of work on TBAs in Africa, including an overview of assessments and management efforts that have taken place over the last half century. New hydrological insights Seventy-two TBAs have been mapped in Africa. They underlie 40% of the continent, where 33% of the population lives, often in arid or semi-arid regions. TBA inventories have progressed since 2000 and remain work in progress. Despite their importance only eleven TBAs have been subjected to more detailed studies. Cooperation has been formalised for seven TBAs. Most of these TBAs are in North Africa and the Sahel. The recent global Transboundary Waters Assessment Programme compiled information at the national level to describe TBAs in terms of key indicators related to the water resource, socio-economic, and legal and institutional conditions. Availability of data at national level is low, hampering regional assessment. Comparing indicators, from questionnaire surveys, with those from a global water-use model showed variable levels of agreement, calling for further research. Reports on agreements scoping TBA management, indicate that this may be dealt with within international river/lake agreements, but reported inconsistencies between TBA sharing countries also indicate that implementation is limited. Increasing awareness and support to joint TBA management is noticeable amongst international organisations. However, such cooperation requires long-term commitment to produce impacts at the local level. |
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2214-5818 |
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THL @ christoph.kuells @ nijsten_transboundary_2018 |
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93 |
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Orloff, K.G.; Mistry, K.; Charp, P.; Metcalf, S.; Marino, R.; Shelly, T.; Melaro, E.; Donohoe, A.M.; Jones, R.L. |
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Human exposure to uranium in groundwater |
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2004 |
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Environmental Research |
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94 |
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3 |
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319-326 |
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Groundwater, Human exposure, Uranium, Urine |
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High concentrations of uranium (mean=620μg/L) were detected in water samples collected from private wells in a residential community. Based on isotopic analyses, the source of the uranium contamination appeared to be from naturally occurring geological deposits. In homes where well water concentrations of uranium exceeded the drinking water standard, the residents were advised to use an alternate water source for potable purposes. Several months after the residents had stopped drinking the water, urine samples were collected and tested for uranium. Elevated concentrations of uranium (mean=0.40μg/g creatinine) were detected in urine samples, and 85 percent of the urine uranium concentrations exceeded the 95th percentile concentration of a national reference population. Urine uranium concentrations were positively correlated with water uranium concentrations, but not with the participants’ ages or how long they had been drinking the water. Six months later, a second urine sample was collected and tested for uranium. Urine uranium concentrations decreased in most (63 percent) of the people. In those people with the highest initial urine uranium concentrations, the urine levels decreased an average of 78 percent. However, urine uranium concentrations remained elevated (mean=0.27μg/g), and 87 percent of the urine uranium concentrations exceeded the 95th percentile concentration of the reference population. The results of this investigation demonstrated that after long-term ingestion of uranium in drinking water, elevated concentrations of uranium in urine could be detected up to 10 months after exposure had stopped. |
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0013-9351 |
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THL @ christoph.kuells @ orloff_human_2004 |
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136 |
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Paradis, C.J.; Hoss, K.N.; Meurer, C.E.; Hatami, J.L.; Dangelmayr, M.A.; Tigar, A.D.; Johnson, R.H. |
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Elucidating mobilization mechanisms of uranium during recharge of river water to contaminated groundwater |
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2022 |
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Journal of Contaminant Hydrology |
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251 |
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104076 |
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Desorption, Dissolution, Groundwater, Surface water, Tracer, Uranium |
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The recharge of stream water below the baseflow water table can mobilize groundwater contaminants, particularly redox-sensitive and sorptive metals such as uranium. However, in-situ tracer experiments that simulate the recharge of stream water to uranium-contaminated groundwater are lacking, thus limiting the understanding of the potential mechanisms that control the mobility of uranium at the field scale. In this study, a field tracer test was conducted by injecting 100 gal (379 l) of oxic river water into a nearby suboxic and uranium-contaminated aquifer. The traced river water was monitored for 18 days in the single injection well and in the twelve surrounding observation wells. Mobilization of uranium from the solid to the aqueous phase was not observed during the tracer test despite its pre-test presence being confirmed on the aquifer sediments from lab-based acid leaching. However, strong evidence of oxidative immobilization of iron and manganese was observed during the tracer test and suggested that immobile uranium was likely in its oxidized state as U(VI) on the aquifer sediments; these observations ruled out oxidation of U(IV) to U(VI) as a potential mobilization mechanism. Therefore, desorption of U(VI) appeared to be the predominant potential mobilization mechanism, yet it was clearly not solely dependent on concentration as evident when considering that uranium-poor river water (\textless0.015 mg/L) was recharged to uranium-rich groundwater (≈1 mg/L). It was possible that uranium desorption was limited by the relatively higher pH and lower alkalinity of the river water as compared to the groundwater; both factors favor immobilization. However, it was likely that the immobile uranium was associated with a mineral phase, as opposed to a sorbed phase, thus desorption may not have been possible. The results of this field tracer study successfully ruled out two common mobilization mechanisms of uranium: (1) oxidative dissolution and (2) concentration-dependent desorption and ruled in the importance of advection, dispersion, and the mineral phase of uranium. |
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0169-7722 |
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THL @ christoph.kuells @ paradis_elucidating_2022 |
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135 |
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