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Author Abiye, T. url  openurl
  Title Synthesis on groundwater recharge in Southern Africa: A supporting tool for groundwater users Type Journal Article
  Year 2016 Publication Groundwater for Sustainable Development Abbreviated Journal  
  Volume 2-3 Issue Pages 182-189  
  Keywords Arid and semi-arid areas, Groundwater recharge, Recharge estimation methods, Southern Africa  
  Abstract This synthesis on groundwater recharge targets the Southern African region as a result of the dependence of the community and economic sector on the groundwater resource. Several literature based recharge studies were collected and assessed in order to find out the main controls to the occurrence of recharge. The Water Table Fluctuation and Base flow separation methods have been tested in the catchment that drains crystalline basement rocks and dolostones close to the city of Johannesburg, South Africa. Based on the assessed data the Chloride Mass Balance method resulted in groundwater recharge of less than 4% of the rainfall, while it reaches 20%, when rainfall exceeds 600mm. For the classical water balance method, recharge proportion is less than 3% of rainfall as a result of very high ambient temperature in the region. Based on the Saturated Volume Fluctuation and Water Table Fluctuation methods, recharge could be less than 6% for annual rainfall of less than 600mm. Observational results further suggest that sporadic recharge from high intensity rainfall has important contribution to the groundwater recharge in the region, owing to the presence of permeable geological cover, which could not be fully captured by most of the recharge estimation methods. This study further documents an evaluation of the most reliable recharge estimation methods in the area such as the chloride mass balance, saturated volume fluctuation and water table fluctuation methods in order to successfully manage the groundwater resource.  
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  ISSN 2352-801x ISBN (up) Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ abiye_synthesis_2016 Serial 101  
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Author Chase, B.M.; Meadows, M.E. url  openurl
  Title Late Quaternary dynamics of southern Africa’s winter rainfall zone Type Journal Article
  Year 2007 Publication Earth-Science Reviews Abbreviated Journal  
  Volume 84 Issue 3 Pages 103-138  
  Keywords Last Glacial Maximum, palaeoenvironment, Quaternary, southern Africa, westerlies, winter rainfall zone  
  Abstract Variations in the nature and extent of southern Africa’s winter rainfall zone (WRZ) have the potential to provide important information concerning the nature of long-term climate change at both regional and hemispheric scales. Positioned at the interface between tropical and temperate systems, southern Africa’s climate is influenced by shifts in the Intertropical Convergence Zone, the westerlies, and the development and position of continental and oceanic anticyclones. Over the last glacial–interglacial cycle substantial changes in the amount and seasonality of precipitation across the subcontinent have been linked to the relative dominance of these systems. Central to this discussion has been the extent to which the region’s glacial climates would have been affected by expansions of Antarctic sea-ice, equatorward migrations of the westerlies, more frequent/intense winter storms and an expanded WRZ. This paper reviews the developing body of evidence pertaining to shifts in the WRZ, and the evolution of ideas that have been presented to explain the patterns observed. Dividing the region into three separate axes, along the western and southern margins of the continent and across the interior into the Karoo and the Kalahari, a range of evidence from both terrestrial sites and marine cores is considered, and potential expansions of the WRZ expansions are explored. Despite the limitations of many of the region’s proxy records, a coherent pattern has begun to develop of a significantly expanded WRZ during phases of the last glacial period, with the best-documented being between 32–17 ka. While more detailed inferences will require the recovery and analysis of longer and better-dated records, this synthesis provides a new baseline for further research in this key region.  
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  ISSN 0012-8252 ISBN (up) Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ chase_late_2007 Serial 102  
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Author Kharaka, Y.; Harmon, R.; Darling, G. url  openurl
  Title W. Mike Edmunds (1941–2015) Type Journal Article
  Year 2015 Publication Applied Geochemistry Abbreviated Journal  
  Volume 59 Issue Pages 225-226  
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  ISSN 0883-2927 ISBN (up) Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ kharaka_w_2015 Serial 103  
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Author Belz, L.; Schüller, I.; Wehrmann, A.; Köster, J.; Wilkes, H. url  openurl
  Title The leaf wax biomarker record of a Namibian salt pan reveals enhanced summer rainfall during the Last Glacial-Interglacial Transition Type Journal Article
  Year 2020 Publication Palaeogeography, Palaeoclimatology, Palaeoecology Abbreviated Journal  
  Volume 543 Issue Pages 109561  
  Keywords -Alkanes, -Alkanols, Late Quaternary, Organic geochemistry, Palaeohydrology, Southern Africa  
  Abstract Conventional continental geoarchives are rarely available in arid southern Africa. Therefore, palaeoclimate data in this area are still patchy and late Quaternary climate development is only poorly understood. In the western Kalahari, salt pans (playas, ephemeral lakes) are common and can feature quasi-continuous sedimentation. This study presents the first climate-related biomarker record using sediments from the Omongwa Pan, a Kalahari salt pan located in eastern Namibia. Our approach to reconstruct vegetation and hydrology focuses on biogeochemical bulk parameters and plant wax-derived lipid biomarkers (n-alkanes, n-alkanols, and fatty acids) and their compound-specific carbon and hydrogen isotopic compositions. The presented record reaches back to 27 ka. During the glacial, rather low δ2H values of n-alkanes and low sediment input exclude a strong influence of winter rainfall. n-Alkane and n-alkanol distributions and δ13C values of n-hentriacontane (n-C31) indicate a shift to a vegetation with a higher proportion of C4 plants at the end of the Last Glacial Maximum until the end of Heinrich Stadial I (ca. 18–14.8 ka), which we interpret to indicate an abrupt excursion to a short wetter period likely to be caused by a temporary southward shift of the Intertropical Convergence Zone. Shifts in δ2H values of n-C31 and plant wax parameters give evidence for changes to drier conditions during early Holocene. Comparison of this dataset with representative continental records from the region points to a major influence of summer rainfall at Omongwa Pan during the regarded time span and demonstrates the potential of southern African salt pans as archives for biomarker-based climate proxies.  
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  ISSN 0031-0182 ISBN (up) Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ belz_leaf_2020 Serial 104  
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Author Tujchneider, O.; Christelis, G.; Gun, J.V. der url  openurl
  Title Towards scientific and methodological innovation in transboundary aquifer resource management Type Journal Article
  Year 2013 Publication Environmental Development Abbreviated Journal  
  Volume 7 Issue Pages 6-16  
  Keywords Communication, Cooperation, Holistic methodological approach, Science, Transboundary aquifer management  
  Abstract Groundwater is both an invaluable and a vulnerable resource. Aquifer resources management, aiming at the responsible exploitation and adequate protection of the groundwater resources, is therefore of key importance and has to be based on sound hydrological, environmental, economic and social principles. Aquifer-wide groundwater projects are carried out to collect the required area-specific information, to understand ongoing processes, to identify the management issues to be addressed and to develop an adequate management strategy and action plan. The quality of the project results depends to a large extent on the science and methodologies adopted in the design and used during the implementation of the projects. In this context, a project was carried out recently to analyse the scientific aspects of—among others—the transboundary aquifer projects within the IW: Portfolio of the Global Environmental Facility (GEF) and to make recommendations for scientific strengthening and innovation. This paper presents the main outcomes of this analysis. In order to accomplish groundwater resources management goals in the case of transboundary aquifers, a balanced joint strategy is needed. Analysis of documentation on completed and on-going transboundary aquifer projects has shown a wide range of scientific activities that contribute positively to the development of such strategies. This analysis has also identified options for increasing the positive impacts of science on strategy development; some of these options have been pioneered already and deserve wider application other ones are relatively new. Important options are: integrating transboundary aquifer resource management in a wider environmental–socio-economical context (holistic approach); exploring causal chains to better understand the processes of change of groundwater resources; using this improved understanding for optimising groundwater assessment and monitoring programmes; and adaptive management. In addition, to obtain maximum benefit of the scientific results there is a general need to promote effective communication at all levels, between the scientific community and policy-/decision makers, as well as with the local community who have a major role to play in the use and conservation of the resources. All of this should be accompanied by the harmonisation of the legal instruments and co-operation agreements between countries and the communities involved. Two case studies, one in South America and one in Southern Africa, are added as examples of the setting and approach of the analysed transboundary aquifer projects.  
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  ISSN 2211-4645 ISBN (up) Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ tujchneider_towards_2013 Serial 105  
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Author Lim, S.; Chase, B.M.; Chevalier, M.; Reimer, P.J. url  openurl
  Title 50,000years of vegetation and climate change in the southern Namib Desert, Pella, South Africa Type Journal Article
  Year 2016 Publication Palaeogeography, Palaeoclimatology, Palaeoecology Abbreviated Journal  
  Volume 451 Issue Pages 197-209  
  Keywords Climate reconstruction, Late Quaternary, Namib Desert, Pollen, Rock hyrax middens, South Africa  
  Abstract This paper presents the first continuous pollen record from the southern Namib Desert spanning the last 50,000years. Obtained from rock hyrax middens found near the town of Pella, South Africa, these data are used to reconstruct vegetation change and quantitative estimates of temperature and aridity. Results indicate that the last glacial period was characterised by increased water availability at the site relative to the Holocene. Changes in temperature and potential evapotranspiration appear to have played a significant role in determining the hydrologic balance. The record can be considered in two sections: 1) the last glacial period, when low temperatures favoured the development of more mesic Nama-Karoo vegetation at the site, with periods of increased humidity concurrent with increased coastal upwelling, both responding to lower global/regional temperatures; and 2) the Holocene, during which time high temperatures and potential evapotranspiration resulted in increased aridity and an expansion of the Desert Biome. During this latter period, increases in upwelling intensity created drier conditions at the site. Considered in the context of discussions of forcing mechanisms of regional climate change and environmental dynamics, the results from Pella stand in clear contrast with many inferences of terrestrial environmental change derived from regional marine records. Observations of a strong precessional signal and interpretations of increased humidity during phases of high local summer insolation in the marine records are not consistent with the data from Pella. Similarly, while high percentages of Restionaceae pollen has been observed in marine sediments during the last glacial period, they do not exceed 1% of the assemblage from Pella, indicating that no significant expansion of the Fynbos Biome has occurred during the last 50,000years. These findings pose interesting questions regarding the nature of environmental change in southwestern Africa, and the significance of the diverse records that have been obtained from the region.  
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  ISSN 0031-0182 ISBN (up) Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ lim_50000years_2016 Serial 107  
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Author Stone, A. url  openurl
  Title Recharge investigations above the Stampriet Aquifer in semi-arid Namibia using geochemical methods and environmental tracers; sand, salt and water Type Journal Article
  Year 2012 Publication Quaternary International Abbreviated Journal  
  Volume 279-280 Issue Pages 470-471  
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  ISSN 1040-6182 ISBN (up) Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ stone_recharge_2012 Serial 108  
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Author Castro, M.C.; Stute, M.; Schlosser, P. url  openurl
  Title Comparison of 4He ages and 14C ages in simple aquifer systems: implications for groundwater flow and chronologies Type Journal Article
  Year 2000 Publication Applied Geochemistry Abbreviated Journal  
  Volume 15 Issue 8 Pages 1137-1167  
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  Abstract 4He concentrations in excess of the solubility equilibrium with the atmosphere by up to two to three orders of magnitude are observed in the Carrizo Aquifer in Texas, the Ojo Alamo and Nacimiento aquifers in the San Juan Basin, New Mexico, and the Auob Sandstone Aquifer in Namibia. A simple 4He accumulation model is applied to explain these excess 4He concentrations in terms of both in situ production and a crustal flux across the bottom layer of the aquifer. Results from the model simulations suggest variability in the 4He fluxes, ranging from 6×10−6 cm3 STP cm−2 yr−1 for the Auob Sandstone Aquifer to 3.6×10−7 cm3 STP cm−2 yr−1 for the Carrizo aquifer. For the Ojo Alamo and Nacimiento aquifers an intermediate value of 3×10−6 cm3 STP cm−2 yr−1 was estimated. The contribution of in-situ produced 4He to the measured concentrations was also estimated. This contribution is negligible for the Auob Sandstone Aquifer as compared with both the concentrations measured at the top and bottom of the aquifer for most of the pathway. In the Carrizo aquifer, in-situ produced 4He contributes 27.5% and 15.4%, to the total 4He observed at the top and bottom of the aquifer, respectively. For both aquifers of the San Juan Basin in-situ production almost entirely dominates the 4He concentrations at the top of the aquifer for most of the pathway. In contrast, the internal production is negligible as compared with the measured concentrations at the bottom of these aquifers, reaching, at most, 1.1%. The model simulations require an exponential decrease in the horizontal velocity of the water with increasing recharge distance to reproduce the distribution of 4He in these aquifers. For the Auob Sandstone Aquifer the highest range in the velocity values is obtained (25 to 0.4 m yr−1). The simulations for the Carrizo aquifer and both aquifers located in the San Juan Basin require velocities varying from 4 to 0.1 m yr−1, and from 2 to 0.3 m yr−1, respectively. For each aquifer, average permeability values were also estimated. They are generally in agreement with results obtained from pumping tests, hydrodynamic modeling and previous 14C measurements. On the basis of the results obtained by calibrating the model with the measured 4He concentrations, the mean water residence times were estimated. They agree reasonably well with 14C ages. When applied as chronologies for noble gas temperatures in the same aquifers, the calculated 4He ages allow the identification of three different climate periods similar to those previously identified using 14C ages: (1) the Holocene period (0–10 Ka BP), (2) the Last Glacial Maximum (≈18 Ka BP), and (3) the preceeding period (30–150 Ka BP).  
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  Call Number THL @ christoph.kuells @ castro_comparison_2000 Serial 109  
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Author Brook, G.A.; Railsback, L.B.; Marais, E. url  openurl
  Title Reassessment of carbonate ages by dating both carbonate and organic material from an Etosha Pan (Namibia) stromatolite: Evidence of humid phases during the last 20ka Type Journal Article
  Year 2011 Publication Quaternary International Abbreviated Journal  
  Volume 229 Issue 1 Pages 24-37  
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  Abstract Previous research on lacustrine stromatolites from Etosha Pan in Namibia obtained ages on carbonate close to or beyond the limits of radiocarbon dating. These ages suggested that the basin was likely not subject to extensive flooding during the last ca. 40ka. This study shows that AMS radiocarbon ages for the carbonate of a stromatolite from Poacher’s Point are 15–21ka older than ages for organic material in the stromatolite structure. Calibrated ages range from 30 to 40ka for carbonate and 3–19ka for the organic residue. The new ages, together with petrographic and isotopic data for the stromatolite, have provided important new information on past flooding of Etosha Pan including evidence of prolonged lacustrine conditions during the Holocene Climatic Optimum.  
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  ISSN 1040-6182 ISBN (up) Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ brook_reassessment_2011 Serial 110  
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Author Hall, S.M.; Gosen, B.S.V.; Zielinski, R.A. url  openurl
  Title Sandstone-hosted uranium deposits of the Colorado Plateau, USA Type Journal Article
  Year 2023 Publication Ore Geology Reviews Abbreviated Journal  
  Volume 155 Issue Pages 105353  
  Keywords Colorado, Plateau, Uranium, Vanadium  
  Abstract More than 4,000 sandstone-hosted uranium occurrences host over 1.2 billion pounds of mined and in situ U3O8 throughout the Colorado Plateau. Most of the resources are in two distinct mineral systems with deposits hosted in the Triassic Chinle and Jurassic Morrison Formations. In the Chinle mineral system, base metal sulfides typically accompany mineralization. The Morrison mineral system is characterized by V/U ratios up to 20. The uranium source was likely volcanic ash preserved as bentonitic mudstones in the Brushy Basin Member of the Morrison Formation, and lithic volcanic clasts, ash shards, and bentonitic clay in the lower part of the Chinle Formation. Vanadium originated from two possible sources: iron–titanium oxides that are extensively altered in bleached rock near deposits or from similar minerals in variably bleached red beds interbedded with and beneath the Morrison. In Chinle-hosted deposits, in addition to volcanic ash, a contributing source of both vanadium and uranium is proposed here for the first time to be underlying red beds in the Moenkopi and Cutler Formations that have undergone a cycle of reddening-bleaching-reoxidation. Transport in both systems was likely in groundwater through the more permeable sandstones and conglomerate units. The association of uranium minerals with carbonate and more rarely apatite, suggests that transport of uranium was as a carbonate or phosphate complex. The first comprehensive examination of paleoclimate, paleotopography, and subsurface structure of aquifers coupled with analysis of the geochronology of deposits suggests that that there were distinct pulses of uranium mineralization/redistribution during the period from about 259 Ma to 12 Ma when oxidized mineralizing fluids were intermittently rejuvenated in the Plateau in response to changes in tectonic regime and climate. Multiple lines of evidence indicate that deposits formed at ambient temperatures of about 25 °C to no greater than about 140 °C. In both systems, deposits formed where groundwater flow slowed and was subject to evaporative concentration. Stagnant conditions allowed for prolonged interaction of U- and V-enriched groundwater with ferrous iron-bearing reductants, such as illite and iron–titanium oxides, and more rarely organic material such as plant debris. Paragenetically late in the sequence, reducing fluids introduced additional organic matter to some deposits. Reducing fluids and introduced organic matter (now amorphous and altered by radiolysis) may originate from regional petroleum systems where peak oil and gas generation was from ∼ 82 to ∼ 5 Ma. Our novel analysis indicates that these reducing fluids bleached rock and protected affected deposits from remobilization during exposure and weathering that followed uplift of the Plateau (∼80 to 40 Ma).  
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  ISSN 0169-1368 ISBN (up) Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ hall_sandstone-hosted_2023 Serial 111  
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