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Author Mabrouk, M.; Han, H.; Fan, C.; Abdrabo, K.I.; Shen, G.; Saber, M.; Kantoush, S.A.; Sumi, T. url  openurl
  Title Assessing the effectiveness of nature-based solutions-strengthened urban planning mechanisms in forming flood-resilient cities Type Journal Article
  Year 2023 Publication Journal of Environmental Management Abbreviated Journal  
  Volume 344 Issue Pages 118260  
  Keywords Flood, Urban planning, Sustainable cities, LID, Natural-based solutions, Alexandria  
  Abstract (up) Cities have experienced rapid urbanization-induced harsh climatic events, especially flooding, inevitably resulting in negative and irreversible consequences for urban resilience and endangering residents’ lives. Numerous studies have analyzed the effects of anthropogenic practices (land use changes and urbanization) on flood forecasting. However, non-structural mitigation’s effectiveness, like Nature-Based Solutions (NBS), has yet to receive adequate attention, particularly in the Middle East and North Africa (MENA) region, which have become increasingly significant and indispensable for operationalizing cities efficiently. Therefore, our study investigated the predictive influence of incorporating one of the most common NBS strategies called low-impact development tools (LID) (such as rain gardens, bio-retention cells, green roofs, infiltration trenches, permeable pavement, and vegetative swale) during the urban planning of Alexandria, Egypt, which experiences the harshest rainfall annually and includes various urban patterns. City characteristics-dependent 14 LID scenarios were simulated with recurrence intervals ranging from 2 to 100 years using the LID Treatment Train Tool (LID TTT), depending on calibrated data from 2015 to 2020, by the Nash-Sutcliffe efficiency index and deterministic coefficient, and root-mean-square error with values of 0.97, 0.91, and 0.31, respectively. Our findings confirmed the significant effectiveness of combined LID tools on total flood runoff volume reduction by 73.7%, revealing that different urban patterns can be used in flood-prone cities, provided LID tools are considered in city planning besides grey infrastructure to achieve optimal mitigation. These results, which combined multiple disciplines and were not explicitly mentioned in similar studies in developing countries, may assist municipalities’ policymakers in planning flood-resistant, sustainable cities.  
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  Series Volume Series Issue Edition  
  ISSN 0301-4797 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Mabrouk2023118260 Serial 232  
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Author Hebert, B.; Baron, F.; Robin, V.; Lelievre, K.; Dacheux, N.; Szenknect, S.; Mesbah, A.; Pouradier, A.; Jikibayev, R.; Roy, R.; Beaufort, D. url  openurl
  Title Quantification of coffinite (USiO4) in roll-front uranium deposits using visible to near infrared (Vis-NIR) portable field spectroscopy Type Journal Article
  Year 2019 Publication Journal of Geochemical Exploration Abbreviated Journal  
  Volume 199 Issue Pages 53-59  
  Keywords Coffinite, Mineral quantification, Near infrared, Ore exploration, Portable field spectroscopy, Roll-front deposits  
  Abstract (up) Coffinite (USiO4) is a common uranium-bearing mineral of roll-front uranium deposits. This mineral can be identified by the visible near infrared (Vis-NIR) portable field spectrometers used in mining exploration. However, due to the low detection limits and associated errors, the quantification of coffinite abundance in the mineralized sandstones or sandy sediments of roll-front uranium deposits using Vis-NIR spectrometry requires a specific methodological development. In this study, the 1135 nm absorption band area is used to quantify the abundance of coffinite. This absorption feature does not interfere with NIR absorption bands of any other minerals present in natural sands or sandstones of uranium roll-front deposits. The correlation between the 1135 nm band area and coffinite content was determined from a series of spectra measured from prepared mineral mixtures. The samples were prepared with a range of weighted amounts of arenitic sands and synthetic coffinite simulating the range of uranium concentration encountered in roll-front uranium deposits. The methodology presented in this study provides the quantification of the coffinite content present in sands between 0.03 wt% to 1 wt% coffinite with a detection limit as low as 0.005 wt%. The integrated area of the 1135 nm band is positively correlated with the coffinite content of the sand in this range, showing that the method is efficient to quantify coffinite concentrations typical of roll-front uranium deposits. The regression equation defined in this study was then used as a reference to predict the amount of natural coffinite in a set of mineralized samples from the Tortkuduk uranium roll-front deposit (South Kazakhstan).  
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  ISSN 0375-6742 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ hebert_quantification_2019 Serial 184  
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Author Soh, Q.Y.; O’Dwyer, E.; Acha, S.; Shah, N. url  openurl
  Title Robust optimisation of combined rainwater harvesting and flood mitigation systems Type Journal Article
  Year 2023 Publication Water Research Abbreviated Journal  
  Volume 245 Issue Pages 120532  
  Keywords Rainwater harvesting, Flood mitigation, Robust stochastic optimisation, Sustainable environmental engineering, Decision tool, Urban residential estates  
  Abstract (up) Combined large-scale rainwater harvesting (RWH) and flood mitigation systems are promising as a sustainable water management strategy in urban areas. These are multi-purpose infrastructure that not only provide a secondary, localised water resource, but can also reduce discharge and hence loads on any downstream wastewater networks if these are integrated into the wider water network. However, the performance of these systems is dependent on the specific design used for its local catchment which can vary significantly between different implementations. A multitude of design strategies exist, however there is no universally accepted standard framework. To tackle these issues, this paper presents a two-player optimisation framework which utilises a stochastic design optimisation model and a competing, high-intensity rainfall design model to optimise passively-operated RWH systems. A customisable tool set is provided, under which optimisation models specific to a given catchment can be built quickly. This reduces the barriers to implementing computationally complex sizing strategies and encouraging more resource-efficient systems to be built. The framework was applied to a densely populated high-rise residential estate, eliminating overflow events from historical rainfall. The optimised configuration resulted in a 32% increase in harvested water yield, but its ability to meet irrigation demands was limited by the operational levels of the treatment pump. Hence, with the inclusion of operational levels in the optimisation model, the framework can provide an efficient large-scale RWH system that is capable of simultaneously meeting water demands and reducing stresses within and beyond its local catchment.  
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  Series Volume Series Issue Edition  
  ISSN 0043-1354 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Soh2023120532 Serial 243  
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Author Kharazi, P.; khazaeli, E.A.; Heshmatpour, A. url  openurl
  Title Delineation of suitable sites for groundwater dams in the semi-arid environment in the northeast of Iran using GIS-based decision-making method Type Journal Article
  Year 2021 Publication Groundwater for Sustainable Development Abbreviated Journal  
  Volume 15 Issue Pages 100657  
  Keywords Subsurface dam, Hybrid decision-making method, Geographic information system, Analytical hierarchy process, EDAS, TOPSIS1  
  Abstract (up) Competing commercial demands on water resources need to be balanced as the world’s population rises. Generally, groundwater is raised by subsurface dams. In this paper, the geographic information system (GIS) software and a decision-making method were applied. As the first step, the limitations that affect the establishment of the subsurface dam were identified using eliminating criteria by the Boolean logic. Regarding the second step, the most appropriate axis was determined for subsurface dam construction in each of the limits. The analytical hierarchy process (AHP) was applied according to the evaluation criteria in this study. The aim of using AHP was to weigh and prioritize the criteria of the groundwater dam for recognizing appropriate sites. Among various places and regarding the subsurface dam construction, AHP was conducted using a hierarchy process for finding the most suitable sites in the third stage of the decision-making method. Finally, among the ten appropriate sites, cross comparison was drawn by using Decision Expert (DEX), Evaluation based on Distance from Average Solution (EDAS), and Technique for Order of Preference by Similarity to Ideal Solution (TOPSIS). Compared together (as a process of decision-making), DEX, TOPSIS, and EDAS methods assisted in ranking the most appropriate sites in the final step of subsurface dam pre-selection. A and C axes obtained scores between 1 and 2, among 10 axes according to the numerically ranked locations. Regarding the water shortage issue and better management of the underground water at certain levels, the findings of this study could be useful for the residents of Kajbid-Balaqly Watershed in the dry season. Further, water managers can use the above-mentioned methods for their decisions regarding the proper subsurface dam establishment.  
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  Series Volume Series Issue Edition  
  ISSN 2352-801x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Kharazi2021100657 Serial 250  
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Author Bonnetti, C.; Zhou, L.; Riegler, T.; Brugger, J.; Fairclough, M. url  openurl
  Title Large S isotope and trace element fractionations in pyrite of uranium roll front systems result from internally-driven biogeochemical cycle Type Journal Article
  Year 2020 Publication Geochimica et Cosmochimica Acta Abbreviated Journal  
  Volume 282 Issue Pages 113-132  
  Keywords Activity cycle, Pyrite composition, Roll front uranium deposits, S isotope and trace element fractionation  
  Abstract (up) Complex pyrite textures associated with large changes in isotopic and trace element compositions are routinely assumed to be indicative of multi-faceted processes involving multiple fluid and sulfur sources. We propose that the features of ore-stage pyrite from roll front deposits across the world, revealed in exquisite detail via high-resolution trace element mapping by LA-ICP-MS, reflect the dynamic internal evolution of the biogeochemical processes responsible for sulfate reduction, rather than externally driven changes in fluid or sulfur sources through time. Upon percolation of oxidizing fluids into the reduced host-sandstones, roll front systems become self-organized, with a systematic reset of their activity cycle after each translation stage of the redox interface down dip of the aquifer. Dominantly reducing conditions at the redox interface favor the formation of biogenic framboidal pyrite (δ34S from −30.5 to −12.5‰) by bacterial sulfate reduction and the genesis of the U mineralization. As the oxidation front advances, oxidation of reduced sulfur minerals induces an increased supply of sulfate and metals in solution to the bacterial sulfate reduction zone that has similarly advanced down the flow gradient. Hence, this stage is marked by increased rates of the bacterial sulfate reduction associated with the crystallization of variably As-Co-Ni-Mo-enriched concentric pyrite (up to 10,000′s of ppm total trace contents) with moderately negative δ34S values (from −13.7 to −7.5‰). A final stage of pyrite cement with low trace element contents and heavier δ34S signature (from −6.9 to +18.8‰) marks the end of the roll front activity cycle and the transition from an open to a predominantly closed system behavior (negligible advection of fresh sulfate). Blocky pyrite cement is formed using the remaining sulfate, which now becomes quickly heavy according to a Rayleigh isotope fractionation process. This ends the cycle by depleting the nutrient supplies for the sulfate-reducing bacteria and cementing pore spaces within the host sandstone, effectively restricting fluid infiltration. This internally-driven roll front activity cycle results in systematic, large S isotope and trace element fractionation. Ultimately, the long-time evolution of the basin and fluid sources control the metal endowment and evolution of the system; these events, however, are unlikely to be preserved by the roll front, as a direct result of its hydrodynamic nature.  
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  Series Volume Series Issue Edition  
  ISSN 0016-7037 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ bonnetti_large_2020 Serial 185  
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Author Rosen, M.R.; Burow, K.R.; Fram, M.S. url  openurl
  Title Anthropogenic and geologic causes of anomalously high uranium concentrations in groundwater used for drinking water supply in the southeastern San Joaquin Valley, CA Type Journal Article
  Year 2019 Publication Journal of Hydrology Abbreviated Journal  
  Volume 577 Issue Pages 124009  
  Keywords California, Central Valley, Geochemistry, Groundwater San Joaquin Valley, Uranium  
  Abstract (up) Concentrations of uranium (U) \textgreater30 µg/L in groundwater are relatively uncommon in drinking water in the United States but can be of concern in those areas where complex interactions of aquifer materials and anthropogenic alterations of the natural flow regime mobilize U. High concentrations (\textgreater30 µg/L) of U in the southeastern San Joaquin Valley, California, USA, have been detected in 24 percent of 257 domestic, irrigation, and public-supply wells sampled across an approximately 110,000 km2 area. In this study we evaluated mechanisms for mobilization of U in the San Joaquin Valley proposed in previous studies, confirming mobilization by HCO3 and refuting mobilization by NO3 and we refined our understanding of the geologic sources of U to the scale of individual alluvial fans. The location of high concentrations depends on the interactions of geological U sources from fluvial fans that originate in the Sierra Nevada to the east and seepage of irrigation water that contains high concentrations of HCO3 that leaches U from the sediments. In addition, interactions with PO4 from fertilized irrigated fields may sequester U in the aquifer. Principal component analysis of the data demonstrates that HCO3 and ions associated with high total dissolved solids in the aquifer and the percentage of agriculture near the well sampled are associated with high U concentrations. Nitrate concentrations do not appear to control release of U to the aquifer. Age dating of the groundwater and generally increasing U concentrations of the past 25 years in resampled wells where irrigation is prevalent suggests that high U concentrations are associated with younger water, indicating that irrigation of fields over the past 100 years has significantly contributed to increasing concentrations and mobilizing U. In some places, the groundwater is supersaturated with uranyl-containing minerals, as would be expected in roll front deposits. In general, the interaction of natural geological sources high in U, the anthropogenically driven addition of HCO3 and possibly phosphate fertilizer, control the location and concentration of U in each individual fluvial fan, but the addition of nitrate in fertilizer does not appear control the location of high U. These geochemical interactions are complex but can be used to determine controls on anomalously high U in alluvial aquifers.  
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  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ rosen_anthropogenic_2019 Serial 158  
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Author Weerahewa, J.; Timsina, J.; Wickramasinghe, C.; Mimasha, S.; Dayananda, D.; Puspakumara, G. url  openurl
  Title Ancient irrigation systems in Asia and Africa: Typologies, degradation and ecosystem services Type Journal Article
  Year 2023 Publication Agricultural Systems Abbreviated Journal  
  Volume 205 Issue Pages 103580  
  Keywords Agriculture, Climate change, Hydrology, Village tank cascade system, Tank irrigation, Watershed  
  Abstract (up) CONTEXT Ancient irrigation systems (AISs) have been providing a multitude of ecosystem services to rural farming and urban communities in Asia and Africa, especially in arid and semi-arid climatic areas with low rainfall. Many AISs, however have now been degraded. A systematic analysis of AISs on their typologies, causes of degradation, and their ecosystem services is lacking. OBJECTIVE The objective of this review was to synthesize the knowledge on AISs on their typologies, status and causes of degradation, ecosystem services and functions, and identify gaps in research in Asia and Africa. METHOD A critical review of peer-reviewed journal papers, conference and workshop proceedings, book chapters, grey literature, and country reports was conducted. Qualitative and quantitative information from journal papers were used to conceptualize the typologies and analyze the status and causes of degradation, and ecosystems services and functions provided by the AISs. RESULTS AND CONCLUSION Based on the review, we classified AISs into three groups by source of irrigation water: Rainwater harvesting system (RHS) with small reservoirs, ground water based system, and floodwater based system. The RHSs, which used to receive reliable rainfall and managed by well cohesive social organizations for their maintenance and functioning in past, have now been silting due to extreme rainfall pattern and breakdown of the cohesive organizations in recent decades. In ground water based systems, indiscriminate development of deep tube wells causing siltation of channels has been a major challenge. In floodwater irrigation systems, irregular rainfall in the highlands and the breakage of irrigation structures by destructive floods were the main causes of degradation. Lack of maintenance and increased soil erosion, inadequate skilled manpower, and declining support from the government for repair and maintenance were the main causes of degradation of all AISs. The main ecosystem service provided by all AISs is water for agriculture. In tank- and pond-based systems, fish farming is also practiced. Tank irrigation systems provide various types of provisioning, regulatory, cultural and supporting services, especially in India and Sri Lanka. Ground water based systems provide water for domestic purposes and various cultural services. Floodwater based systems provide water for power generation and wildlife habitat maintenance and help in flood control. SIGNIFICANCE The knowledge generated through the review provide evidence-based information, and help aware governments, private sectors and development agencies for improved policy planning and decision making, and prioritizing the restoration, rehabilitation, and management of various AISs.  
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  ISSN 0308-521x ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ Weerahewa2023103580 Serial 275  
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Author Belz, L.; Schüller, I.; Wehrmann, A.; Köster, J.; Wilkes, H. url  openurl
  Title The leaf wax biomarker record of a Namibian salt pan reveals enhanced summer rainfall during the Last Glacial-Interglacial Transition Type Journal Article
  Year 2020 Publication Palaeogeography, Palaeoclimatology, Palaeoecology Abbreviated Journal  
  Volume 543 Issue Pages 109561  
  Keywords -Alkanes, -Alkanols, Late Quaternary, Organic geochemistry, Palaeohydrology, Southern Africa  
  Abstract (up) Conventional continental geoarchives are rarely available in arid southern Africa. Therefore, palaeoclimate data in this area are still patchy and late Quaternary climate development is only poorly understood. In the western Kalahari, salt pans (playas, ephemeral lakes) are common and can feature quasi-continuous sedimentation. This study presents the first climate-related biomarker record using sediments from the Omongwa Pan, a Kalahari salt pan located in eastern Namibia. Our approach to reconstruct vegetation and hydrology focuses on biogeochemical bulk parameters and plant wax-derived lipid biomarkers (n-alkanes, n-alkanols, and fatty acids) and their compound-specific carbon and hydrogen isotopic compositions. The presented record reaches back to 27 ka. During the glacial, rather low δ2H values of n-alkanes and low sediment input exclude a strong influence of winter rainfall. n-Alkane and n-alkanol distributions and δ13C values of n-hentriacontane (n-C31) indicate a shift to a vegetation with a higher proportion of C4 plants at the end of the Last Glacial Maximum until the end of Heinrich Stadial I (ca. 18–14.8 ka), which we interpret to indicate an abrupt excursion to a short wetter period likely to be caused by a temporary southward shift of the Intertropical Convergence Zone. Shifts in δ2H values of n-C31 and plant wax parameters give evidence for changes to drier conditions during early Holocene. Comparison of this dataset with representative continental records from the region points to a major influence of summer rainfall at Omongwa Pan during the regarded time span and demonstrates the potential of southern African salt pans as archives for biomarker-based climate proxies.  
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  ISSN 0031-0182 ISBN Medium  
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  Call Number THL @ christoph.kuells @ belz_leaf_2020 Serial 104  
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Author Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. url  openurl
  Title Origin and history of nitrate in confined groundwater in the western Kalahari Type Journal Article
  Year 1983 Publication Journal of Hydrology Abbreviated Journal  
  Volume 62 Issue 1 Pages 243-262  
  Keywords  
  Abstract (up) Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr.  
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  Series Volume Series Issue Edition  
  ISSN 0022-1694 ISBN Medium  
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  Notes Approved no  
  Call Number THL @ christoph.kuells @ heaton_origin_1983 Serial 95  
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Author Heaton, T.H.E.; Talma, A.S.; Vogel, J.C. url  openurl
  Title Origin and history of nitrate in confined groundwater in the western Kalahari Type Journal Article
  Year 1983 Publication Journal of Hydrology Abbreviated Journal  
  Volume 62 Issue 1 Pages 243-262  
  Keywords  
  Abstract (up) Data are presented for nitrate, dinitrogen and argon concentrations and 15N14N ratios in groundwater, with radiocarbon ages up to 40,000 yr. for three confined sandstone aquifers in the western Kalahari of South West Africa/Namibia. The nitrate is probably generated within the soil of the recharge areas, and its production rate during the period 3000-40,000 B.P. has remained between 0.5 and 1.6 meq NO−3l−1 of recharge water, with ° 15N between + 4 and + 8‰. Variations in the amount of nitrate and of “excess air” in groundwater recharge are found, and can only reflect changes in the environmental conditions during recharge. They must therefore be caused by the climatic changes that have taken place during the past 25,000 yr.  
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  Series Volume Series Issue Edition  
  ISSN 0022-1694 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Heaton1983243 Serial 282  
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