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Author Zeng, S.; Shen, Y.; Sun, B.; Tan, K.; Zhang, S.; Ye, W. url  openurl
  Title Fractal kinetic characteristics of uranium leaching from low permeability uranium-bearing sandstone Type Journal Article
  Year 2022 Publication Nuclear Engineering and Technology Abbreviated Journal  
  Volume 54 Issue 4 Pages 1175-1184  
  Keywords Fractal characteristics, In-situ leaching, Leaching kinetics, Pore structure, Uranium mine  
  Abstract The pore structure of uranium-bearing sandstone is one of the critical factors that affect the uranium leaching performance. In this article, uranium-bearing sandstone from the Yili Basin, Xinjiang, China, was taken as the research object. The fractal characteristics of the pore structure of the uranium-bearing sandstone were studied using mercury intrusion experiments and fractal theory, and the fractal dimension of the uranium-bearing sandstone was calculated. In addition, the effect of the fractal characteristics of the pore structure of the uranium-bearing sandstone on the uranium leaching kinetics was studied. Then, the kinetics was analyzed using a shrinking nuclear model, and it was determined that the rate of uranium leaching is mainly controlled by the diffusion reaction, and the dissolution rate constant (K) is linearly related to the pore specific surface fractal dimension (DS) and the pore volume fractal dimension (DV). Eventually, fractal kinetic models for predicting the in-situ leaching kinetics were established using the unreacted shrinking core model, and the linear relationship between the fractal dimension of the sample’s pore structure and the dissolution rate during the leaching was fitted.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1738-5733 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ zeng_fractal_2022 Serial 193  
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Author Liu, Z.; Tan, K.; Li, C.; Li, Y.; Zhang, C.; Song, J.; Liu, L. url  openurl
  Title Geochemical and S isotopic studies of pollutant evolution in groundwater after acid in situ leaching in a uranium mine area in Xinjiang Type Journal Article
  Year 2023 Publication Nuclear Engineering and Technology Abbreviated Journal  
  Volume 55 Issue 4 Pages 1476-1484  
  Keywords Acid in situ leaching of uranium, Pollution evolution, Sulfate elimination, Sulfur isotopes analysis  
  Abstract Laboratory experiments and point monitoring of reservoir sediments have proven that stable sulfate reduction (SSR) can lower the concentrations of toxic metals and sulfate in acidic groundwater for a long time. Here, we hypothesize that SSR occurred during in situ leaching after uranium mining, which can impact the fate of acid groundwater in an entire region. To test this, we applied a sulfur isotope fractionation method to analyze the mechanism for natural attenuation of contaminated groundwater produced by acid in situ leaching of uranium (Xinjiang, China). The results showed that δ34S increased over time after the cessation of uranium mining, and natural attenuation caused considerable, area-scale immobilization of sulfur corresponding to retention levels of 5.3%–48.3% while simultaneously decreasing the concentration of uranium. Isotopic evidence for SSR in the area, together with evidence for changes of pollutant concentrations, suggest that area-scale SSR is most likely also important at other acid mining sites for uranium, where retention of acid groundwater may be strengthened through natural attenuation. To recapitulate, the sulfur isotope fractionation method constitutes a relatively accurate tool for quantification of spatiotemporal trends for groundwater during migration and transformation resulting from acid in situ leaching of uranium in northern China.  
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  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 1738-5733 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ liu_geochemical_2023 Serial 192  
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Author Zhang, H.; Gao, J.; Xu, L.; Zhang, X. url  openurl
  Title Case studies of radioactivity of drilling mud for in situ leaching uranium mining in China Type Journal Article
  Year 2022 Publication Journal of Environmental Radioactivity Abbreviated Journal  
  Volume 251-252 Issue Pages 106982  
  Keywords Drilling mud, Exemption management, In situ leaching, Radioactivity  
  Abstract The drilling mud from in situ leaching uranium mining is a type of low-radioactivity waste that contains natural nuclides and other harmful substances. In order to determine whether the drilling mud can meet the requirements of radioactive exemption management standards, field investigations and data simulations were conducted in this study. Two typical uranium mines were selected for onsite investigations. Drilling mud from different layers (i.e., the upper covering layer and ore-bearing layer) and from different stages (e.g., logging stage mud, drilling expansion stage mud, and mixed mud) was sampled. For each sample, the 238U and 226Ra concentrations of the solid components and the U and 226Ra concentrations of the supernatant were analyzed. The results revealed that the highest 238U and 226Ra concentrations of the solid components were 4122 Bq/kg and 4077 Bq/kg, while the 238U and 226Ra concentrations of the mixed drilling mud were all less than 300 Bq/kg. A radioactivity estimation model was established for scenario analysis. Exemption management screening lines of waste drilling mud, which can be used to classify and treat the drilling project according to the deposit’s grade and conditions, were proposed for in situ leaching drilling projects.  
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  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0265-931x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ zhang_case_2022 Serial 191  
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Author Kurmanseiit, M.B.; Tungatarova, M.S.; Royer, J.-J.; Aizhulov, D.Y.; Shayakhmetov, N.M.; Kaltayev, A. url  openurl
  Title Streamline-based reactive transport modeling of uranium mining during in-situ leaching: Advantages and drawbacks Type Journal Article
  Year 2023 Publication Hydrometallurgy Abbreviated Journal  
  Volume 220 Issue Pages 106107  
  Keywords 3D modeling, In-situ leaching, Reactive transport model, Streamlines, Uranium recovery  
  Abstract Reactive transport modeling is known to be computationally intensive when applied to 3D problems. Transforming sequential computing on the computer processor units (CPU) into parallelized computation on the high-performance parallel graphic processor units (GPU) is a classical approach to increasing computational performance. Another complementary approach is to decompose a complex 3D modeling problem into a set of simpler 1D problems using streamline approaches which can be easily parallelized, therefore reducing computation time. This paper investigates solutions to the equations governing dissolution and transport using streamlines coupled with a parallelization approach. In addition, an analytical solution to the dissolution and transfer equations of uranium describing the In-Situ Leaching (ISL) mining recovery is found using an approximation series to the 2nd order. The analytical solution is compared to the 1D numerical resolution along the streamlines and to the 3D simulation results superimposed on the streamline. Both approaches give similar results with a relative error of \textless2 % (2%). The proposed methodology is then applied to a case study in which the classical 3D resolution is compared to the newly suggested streamline solution, demonstrating that the streamline approach increases computational performances by a factor ranging from hundred to thousand depending on the complexity of the grid-block model.  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0304-386x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ kurmanseiit_streamline-based_2023 Serial 190  
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Author Bullock, L.A.; Parnell, J. url  openurl
  Title Selenium and molybdenum enrichment in uranium roll-front deposits of Wyoming and Colorado, USA Type Journal Article
  Year 2017 Publication Journal of Geochemical Exploration Abbreviated Journal  
  Volume 180 Issue Pages 101-112  
  Keywords Molybdenum, Roll-fronts, Selenium, Tellurium, Uranium, Wyoming  
  Abstract Sandstone uranium (U) roll-front deposits of Wyoming and Colorado (USA) are important U resources, and may provide a terrestrial source for critical accessory elements, such as selenium (Se), molybdenum (Mo), and tellurium (Te). Due to their associated toxicity, MoSeTe occurrences in roll-fronts should also be carefully monitored during U leaching and ore processing. While elevated MoSe concentrations in roll-fronts are well established, very little is known about Te occurrence in such deposits. This study aims to establish MoSeTe concentrations in Wyoming and Colorado roll-fronts, and assess the significance of these deposits in an environmental and mineral exploration context. Sampled roll-front deposits, produced by oxidized groundwater transportation through a sandstone, show high MoSe content in specific redox zones, and low Te, relative to crustal means. High Se concentrations (up to 168ppm) are restricted to a narrow band of alteration at the redox front. High Mo content (up to 115ppm) is typically associated with the reduced mineralized nose and seepage zones of the roll-front, ahead of the U orebody. Elevated trace element concentrations are likely sourced from proximal granitic intrusions, tuffaceous deposits, and local pyritic mudstones. Elevated MoSe content in the sampled roll fronts may be regarded as a contaminant in U in-situ recovery and leaching processing, and may pose an environmental threat in groundwaters and soils, so extraction should be carefully monitored. The identification of peak concentrations of MoSe can also act as a pathfinder for the redox front of a roll-front, and help to isolate the U orebody, particularly in the absence of gamma signatures.  
  Address  
  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0375-6742 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ bullock_selenium_2017 Serial 189  
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Author Ingham, E.S.; Cook, N.J.; Cliff, J.; Ciobanu, C.L.; Huddleston, A. url  openurl
  Title A combined chemical, isotopic and microstructural study of pyrite from roll-front uranium deposits, Lake Eyre Basin, South Australia Type Journal Article
  Year 2014 Publication Geochimica et Cosmochimica Acta Abbreviated Journal  
  Volume 125 Issue Pages 440-465  
  Keywords  
  Abstract The common sulfide mineral pyrite is abundant throughout sedimentary uranium systems at Pepegoona, Pepegoona West and Pannikan, Lake Eyre Basin, South Australia. Combined chemical, isotopic and microstructural analysis of pyrite indicates variation in fluid composition, sulfur source and precipitation conditions during a protracted mineralization event. The results show the significant role played by pyrite as a metal scavenger and monitor of fluid changes in low-temperature hydrothermal systems. In-situ micrometer-scale sulfur isotope analyses of pyrite demonstrated broad-scale isotopic heterogeneity (δ34S=−43.9 to +32.4‰VCDT), indicative of complex, multi-faceted pyrite evolution, and sulfur derived from more than a single source. Preserved textures support this assertion and indicate a genetic model involving more than one phase of pyrite formation. Authigenic pyrite underwent prolonged evolution and recrystallization, evidenced by a genetic relationship between archetypal framboidal aggregates and pyrite euhedra. Secondary hydrothermal pyrite commonly displays hyper-enrichment of several trace elements (Mn, Co, Ni, As, Se, Mo, Sb, W and Tl) in ore-bearing horizons. Hydrothermal fluids of magmatic and meteoric origins supplied metals to the system but the geochemical signature of pyrite suggests a dominantly granitic source and also the influence of mafic rock types. Irregular variation in δ34S, coupled with oscillatory trace element zonation in secondary pyrite, is interpreted in terms of continuous variations in fluid composition and cycles of diagenetic recrystallization. A late-stage oxidizing fluid may have mobilized selenium from pre-existing pyrite. Subsequent restoration of reduced conditions within the aquifer caused ongoing pyrite re-crystallization and precipitation of selenium as native selenium. These results provide the first qualitative constraints on the formation mechanisms of the uranium deposits at Beverley North. Insights into depositional conditions and sources of both sulfide and uranium mineralization and an improved understanding of pyrite geochemistry can also underpin an effective vector for uranium exploration at Beverley North and other sedimentary systems of the Lake Eyre Basin, as well as in comparable geological environments elsewhere.  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0016-7037 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ ingham_combined_2014 Serial 188  
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Author Li, X.; Shen, K.; Li, Q.; Deng, Y.; Zhu, P.; Wang, D. url  openurl
  Title Roll-over behavior in current-voltage curve introduced by an energy barrier at the front contact in thin film CdTe solar cell Type Journal Article
  Year 2018 Publication Solar Energy Abbreviated Journal  
  Volume 165 Issue Pages 27-34  
  Keywords AlO HRT layer, Band alignment, CdTe solar cell, Roll-over behavior  
  Abstract Roll-over phenomenon in the current–voltage (J–V) curve is often observed in a CdTe thin film solar cell. The roll-over phenomenon, which is occurred near the open-circuit voltage in a light J–V curve, is due to Schottky energy barrier formed at the CdTe/metal interface in a CdTe solar cell back contact. In this study we report a J–V roll-over phenomenon which is induced by an energy barrier at the front contact of a CdTe solar cell. Two kinds of oxides, namely, Al2O3 and SnO2, were deposited as high-resistance transparent (HRT) layer between the window layer CdS and the fluorine doped tin oxide (FTO) front electrode in CdTe solar cells. These two oxides present much different electronic band alignment with FTO and CdS. SnO2 formed almost no energy barrier with CdS, this allowed smooth transport for photo-generated electrons from CdTe to CdS and FTO. However, Al2O3 formed a high energy barrier with CdS. The rather high energy barrier with a value of 3.43 eV at the CdS/Al2O3 interface induced a J–V roll-over phenomenon in a CdTe thin film solar cell, which dramatically led to a quick decrease for the cell device efficiency. The electron transport at the FTO/Al2O3/CdS interface is governed by tunneling effect. The results presented in this study demonstrate that the band structure at the front electrode plays an important role for the performance of a CdTe thin film solar cell.  
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  Corporate Author Thesis  
  Publisher Place of Publication Editor  
  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0038-092x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ li_roll-over_2018 Serial 187  
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Author Min, M.; Xu, H.; Chen, J.; Fayek, M. url  openurl
  Title Evidence of uranium biomineralization in sandstone-hosted roll-front uranium deposits, northwestern China Type Journal Article
  Year 2005 Publication Ore Geology Reviews Abbreviated Journal  
  Volume 26 Issue 3 Pages 198-206  
  Keywords Biomineralization, China, Roll-front uranium deposit, Sandstone  
  Abstract We show evidence that the primary uranium minerals, uraninite and coffinite, from high-grade ore samples (U3O8\textgreater0.3%) in the Wuyiyi, Wuyier, and Wuyisan sandstone-hosted roll-front uranium deposits, Xinjiang, northwestern China were biogenically precipitated and psuedomorphically replace fungi and bacteria. Uranium (VI), which was the sole electron acceptor, was likely to have been enzymically reduced. Post-mortem accumulation of uranium may have also occurred through physio-chemical interaction between uranium and negatively-charged cellular sites, and inorganic adsorption or precipitation reactions. These results suggest that microorganisms may have played a key role in formation of the sandstone- or roll-type uranium deposits, which are among the most economically significant uranium deposits in the world.  
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  Corporate Author Thesis  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0169-1368 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ min_evidence_2005 Serial 186  
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Author Bonnetti, C.; Zhou, L.; Riegler, T.; Brugger, J.; Fairclough, M. url  openurl
  Title Large S isotope and trace element fractionations in pyrite of uranium roll front systems result from internally-driven biogeochemical cycle Type Journal Article
  Year 2020 Publication Geochimica et Cosmochimica Acta Abbreviated Journal  
  Volume 282 Issue Pages 113-132  
  Keywords Activity cycle, Pyrite composition, Roll front uranium deposits, S isotope and trace element fractionation  
  Abstract Complex pyrite textures associated with large changes in isotopic and trace element compositions are routinely assumed to be indicative of multi-faceted processes involving multiple fluid and sulfur sources. We propose that the features of ore-stage pyrite from roll front deposits across the world, revealed in exquisite detail via high-resolution trace element mapping by LA-ICP-MS, reflect the dynamic internal evolution of the biogeochemical processes responsible for sulfate reduction, rather than externally driven changes in fluid or sulfur sources through time. Upon percolation of oxidizing fluids into the reduced host-sandstones, roll front systems become self-organized, with a systematic reset of their activity cycle after each translation stage of the redox interface down dip of the aquifer. Dominantly reducing conditions at the redox interface favor the formation of biogenic framboidal pyrite (δ34S from −30.5 to −12.5‰) by bacterial sulfate reduction and the genesis of the U mineralization. As the oxidation front advances, oxidation of reduced sulfur minerals induces an increased supply of sulfate and metals in solution to the bacterial sulfate reduction zone that has similarly advanced down the flow gradient. Hence, this stage is marked by increased rates of the bacterial sulfate reduction associated with the crystallization of variably As-Co-Ni-Mo-enriched concentric pyrite (up to 10,000′s of ppm total trace contents) with moderately negative δ34S values (from −13.7 to −7.5‰). A final stage of pyrite cement with low trace element contents and heavier δ34S signature (from −6.9 to +18.8‰) marks the end of the roll front activity cycle and the transition from an open to a predominantly closed system behavior (negligible advection of fresh sulfate). Blocky pyrite cement is formed using the remaining sulfate, which now becomes quickly heavy according to a Rayleigh isotope fractionation process. This ends the cycle by depleting the nutrient supplies for the sulfate-reducing bacteria and cementing pore spaces within the host sandstone, effectively restricting fluid infiltration. This internally-driven roll front activity cycle results in systematic, large S isotope and trace element fractionation. Ultimately, the long-time evolution of the basin and fluid sources control the metal endowment and evolution of the system; these events, however, are unlikely to be preserved by the roll front, as a direct result of its hydrodynamic nature.  
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  Corporate Author Thesis  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0016-7037 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ bonnetti_large_2020 Serial 185  
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Author Hebert, B.; Baron, F.; Robin, V.; Lelievre, K.; Dacheux, N.; Szenknect, S.; Mesbah, A.; Pouradier, A.; Jikibayev, R.; Roy, R.; Beaufort, D. url  openurl
  Title Quantification of coffinite (USiO4) in roll-front uranium deposits using visible to near infrared (Vis-NIR) portable field spectroscopy Type Journal Article
  Year 2019 Publication Journal of Geochemical Exploration Abbreviated Journal  
  Volume 199 Issue Pages 53-59  
  Keywords Coffinite, Mineral quantification, Near infrared, Ore exploration, Portable field spectroscopy, Roll-front deposits  
  Abstract Coffinite (USiO4) is a common uranium-bearing mineral of roll-front uranium deposits. This mineral can be identified by the visible near infrared (Vis-NIR) portable field spectrometers used in mining exploration. However, due to the low detection limits and associated errors, the quantification of coffinite abundance in the mineralized sandstones or sandy sediments of roll-front uranium deposits using Vis-NIR spectrometry requires a specific methodological development. In this study, the 1135 nm absorption band area is used to quantify the abundance of coffinite. This absorption feature does not interfere with NIR absorption bands of any other minerals present in natural sands or sandstones of uranium roll-front deposits. The correlation between the 1135 nm band area and coffinite content was determined from a series of spectra measured from prepared mineral mixtures. The samples were prepared with a range of weighted amounts of arenitic sands and synthetic coffinite simulating the range of uranium concentration encountered in roll-front uranium deposits. The methodology presented in this study provides the quantification of the coffinite content present in sands between 0.03 wt% to 1 wt% coffinite with a detection limit as low as 0.005 wt%. The integrated area of the 1135 nm band is positively correlated with the coffinite content of the sand in this range, showing that the method is efficient to quantify coffinite concentrations typical of roll-front uranium deposits. The regression equation defined in this study was then used as a reference to predict the amount of natural coffinite in a set of mineralized samples from the Tortkuduk uranium roll-front deposit (South Kazakhstan).  
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  Corporate Author Thesis  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0375-6742 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ hebert_quantification_2019 Serial 184  
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