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Ruiz, O.; Thomson, B.; Cerrato, J.M.; Rodriguez-Freire, L. |
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Title |
Groundwater restoration following in-situ recovery (ISR) mining of uranium |
Type |
Journal Article |
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Year |
2019 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
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Volume  |
109 |
Issue |
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Pages |
104418 |
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Keywords |
Aquifer stabilization, Ground water restoration, In-situ leach mining, In-situ recovery, Uranium |
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Abstract |
From 1950 through the early 1980’s New Mexico accounted for roughly half of domestic uranium (U) production for the nuclear power industry and the nation’s weapon programs. Increased interest in nuclear energy has led to proposals for renewed development using both underground mining and uranium in situ recovery (ISR). When feasible, ISR greatly reduces waste generated by the mining and milling processes, however, the ability to restore ground water to acceptable quality after ISR ends is uncertain. This research investigated two methods of stabilizing an aquifer following ISR. Batch and column studies were performed to evaluate chemical and biological methods of stabilization. Columns packed with ore were first leached with an aerated NaHCO3 ground water solution to simulate ISR. Constituents present at elevated concentrations after leaching included molybdenum (Mo), selenium (Se), U, and vanadium (V). Chemical stabilization was studied by passing a phosphate (PO43-) amended solution through the ore to achieve passivation of mineral surfaces by P precipitates. Microbial stabilization was studied by passing a lactate solution through the ore to stimulate growth of anaerobic metal- and sulfate-reducing organisms to reduce U and other elements to less soluble phases. Analyses of the solids from the columns after completion of these experiments by X-ray photo electron spectroscopy (XPS) identified phosphate on samples near the column inlet of the chemically stabilized columns. Microbial populations were characterized by Illumina DNA sequencing and confirmed the presence of metal- and sulfate-reducing organisms. Neither chemical nor microbial stabilization method achieved contaminant immobilization, which is believed due to limited mixing of the stabilization solutions with the contaminated leach solutions. These results emphasize that ground water hydrodynamics, especially mixing, must be considered in aquifer restoration of soluble constituents. |
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THL @ christoph.kuells @ ruiz_groundwater_2019 |
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153 |
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Rossetto, R.; Filippis, G.D.; Borsi, I.; Foglia, L.; Cannata, M.; Criollo, R.; Vázquez-Suñé, E. |
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Title |
Integrating free and open source tools and distributed modelling codes in GIS environment for data-based groundwater management |
Type |
Journal Article |
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Year |
2018 |
Publication |
Environmental Modelling & Software |
Abbreviated Journal |
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Volume |
107 |
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Pages |
210-230 |
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Keywords |
Free and Open Source Software, FREEWAT, Groundwater management, ICT, MODFLOW, QGIS |
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Abstract |
Integrating advanced simulation techniques and data analysis tools in a freeware Geographic Information System (GIS) provides a valuable contribution to the management of conjunctive use of groundwater (the world’s largest freshwater resource) and surface-water. To this aim, we describe here the FREEWAT (FREE and open source software tools for WATer resource management) platform. FREEWAT is a free and open source, QGIS-integrated interface for planning and management of water resources, with specific attention to groundwater. The FREEWAT platform couples the power of GIS geo-processing and post-processing tools in spatial data analysis with that of process-based simulation models. The FREEWAT environment allows storage of large spatial datasets, data management and visualization, and running of several distributed modelling codes (mainly belonging to the MODFLOW family). It simulates hydrologic and transport processes, and provides a database framework and visualization capabilities for hydrochemical analysis. Examples of real case study applications are provided. |
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1364-8152 |
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THL @ christoph.kuells @ rossetto_integrating_2018 |
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92 |
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Author |
Stone, A.E.C.; Edmunds, W.M. |
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Title |
Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia |
Type |
Journal Article |
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Year |
2014 |
Publication |
Journal of Arid Environments |
Abbreviated Journal |
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Volume |
105 |
Issue |
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Pages |
41-51 |
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Keywords |
Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge |
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Abstract |
Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge). |
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0140-1963 |
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THL @ christoph.kuells @ stone_naturally-high_2014 |
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91 |
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Author |
Stone, A.E.C.; Edmunds, W.M. |
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Title |
Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia |
Type |
Journal Article |
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Year |
2014 |
Publication |
Journal of Arid Environments |
Abbreviated Journal |
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Volume |
105 |
Issue |
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Pages |
41-51 |
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Keywords |
Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge |
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Abstract |
Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge). |
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0140-1963 |
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THL @ christoph.kuells @ Stone201441 |
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218 |
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Author |
Stone, A.E.C.; Edmunds, W.M. |
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Title |
Naturally-high nitrate in unsaturated zone sand dunes above the Stampriet Basin, Namibia |
Type |
Journal Article |
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Year |
2014 |
Publication |
Journal of Arid Environments |
Abbreviated Journal |
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Volume |
105 |
Issue |
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Pages |
41-51 |
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Keywords |
Kalahari, Namibia, Nitrate in the unsaturated zone, Stampriet Basin, Transboundary basin, Unsaturated zone recharge |
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Abstract |
Elevated groundwater nitrate levels are common in drylands, often in excess of WHO guidelines, with concern for human and animal health. In light of recent attempts to identify nitrate sources in the Kalahari this paper presents the first unsaturated zone (USZ) nitrate profiles and recharge rate estimates for the important transboundary Stampriet Basin, alongside the first rainfall chemistry records. Elevated subsurface nitrate reaches 100–250 and 250–525 mg/L NO3–N, with NO3–N/Cl of 4–12, indicating input above evapotranspiration. Chloride mass balance recharge rates range from 4 to 27 mm/y, indicating a vertical movement of these nitrate pulses toward the water table over multi-decadal timescales. These profiles are sampled from dune crests, away from high concentrations of animals and without termite mounds. Given low-density animal grazing is unlikely to contribute consistent spot-scale nitrate over decades, these profiles give an initial estimate of naturally-produced concentrations. This insight is important for the management of the Stampriet Basin and wider Kalahari groundwater. This study expands our knowledge about elevated nitrate in dryland USZs, demonstrating that it can occur as pulses, probably in response to transient vegetation cover and that it is not limited to long-residence time USZs with very limited downward moisture flux (recharge). |
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0140-1963 |
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THL @ christoph.kuells @ Stone201441 |
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279 |
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Author |
Mühr-Ebert, E.L.; Wagner, F.; Walther, C. |
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Title |
Speciation of uranium: Compilation of a thermodynamic database and its experimental evaluation using different analytical techniques |
Type |
Journal Article |
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Year |
2019 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
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100 |
Issue |
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Pages |
213-222 |
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Abstract |
Environmental hazards are caused by uranium mining legacies and enhanced radioactivity in utilized groundwater and surface water resources. Knowledge of uranium speciation in these waters is essential for predicting radionuclide migration and for installing effective water purification technology. The validity of the thermodynamic data for the environmental media affected by uranium mining legacies is of utmost importance. Therefore, a comprehensive and consistent database was established according to current knowledge. The uranium data included in the database is based on the NEA TDB (Guillaumont et al., 2003) and is modified or supplemented as necessary e.g. for calcium and magnesium uranyl carbonates. The specific ion interaction theory (Brönsted, 1922) is used to estimate activity constants, which is sufficient for the considered low ionic strengths. The success of this approach was evaluated by comparative experimental investigations and model calculations (PHREEQC (Parkhurst and Appelo, 1999)) for several model systems. The waters differ in pH (2.7–9.8), uranium concentration (10−9-10−4 mol/L) and ionic strength (0.002–0.2 mol/L). We used chemical extraction experiments, ESI-Orbitrap-MS and time-resolved laser-induced fluorescence spectroscopy (TRLFS) to measure the uranium speciation. The latter method is nonintrusive and therefore does not change the chemical composition of the investigated waters. This is very important, because any change of the system under study may also change the speciation. |
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0883-2927 |
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THL @ christoph.kuells @ muhr-ebert_speciation_2019 |
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142 |
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Author |
Priestley, S.C.; Payne, T.E.; Harrison, J.J.; Post, V.E.A.; Shand, P.; Love, A.J.; Wohling, D.L. |
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Title |
Use of U-isotopes in exploring groundwater flow and inter-aquifer leakage in the south-western margin of the Great Artesian Basin and Arckaringa Basin, central Australia |
Type |
Journal Article |
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Year |
2018 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
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98 |
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331-344 |
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Activity ratios, Central Australia, Great Artesian Basin, Hydrogeology, Sequential extraction, Uranium isotopes |
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Abstract |
The distribution of uranium isotopes (238U and 234U) in groundwaters of the south-western margin of the Great Artesian Basin (GAB), Australia, and underlying Arckaringa Basin were examined using groundwater samples and a sequential extraction of aquifer sediments. Rock weathering, the geochemical environment and α-recoil of daughter products control the 238U and 234U isotope distributions giving rise to large spatial variations. Generally, the shallowest aquifer (J aquifer) contains groundwater with higher 238U activity concentrations and 234U/238U activity ratios close to secular equilibrium. However, the source input of uranium is spatially variable as intermittent recharge from ephemeral rivers passes through rocks that have already undergone extensive weathering and contain low 238U activity concentrations. Other locations in the J aquifer that receive little or no recharge contain higher 238U activity concentrations because uranium from localised uranium-rich rocks have been leached into solution and the geochemical environment allows the uranium to be kept in solution. The geochemical conditions of the deeper aquifers generally result in lower 238U activity concentrations in the groundwater accompanied by higher 234U/238U activity ratios. The sequential extraction of aquifer sediments showed that α-recoil of 234U from the solid mineral phases into the groundwater, rather than dissolution of, or exchange with the groundwater accessible minerals in the aquifer, caused enrichment of groundwater 234U/238U activity ratios in the Boorthanna Formation. Decay of 238U in uranium-rich coatings on J aquifer sediments caused resistant phase 234U/238U activity ratio enrichment. The groundwater 234U/238U activity ratio is dependent on groundwater residence time or flow rate, depending on the flow path trajectory. Thus, uranium isotope variations confirmed earlier groundwater flow interpretations based on other tracers; however, spatial heterogeneity, and the lack of clear regional correlations, made it difficult to identify recharge and inter-aquifer leakage. |
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0883-2927 |
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THL @ christoph.kuells @ priestley_use_2018 |
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115 |
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Author |
Silva, M.L. da; Bonotto, D.M. |
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Title |
Uranium isotopes in groundwater occurring at Amazonas State, Brazil |
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Journal Article |
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Year |
2015 |
Publication |
Applied Radiation and Isotopes |
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97 |
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24-33 |
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Amazon area, Dissolved uranium, Groundwater, Tube wells, U/U activity ratio |
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This paper reports the behavior of the dissolved U-isotopes 238U and 234U in groundwater providing from 15 cities in Amazonas State, Brazil. The isotope dilution technique accompanied by alpha spectrometry were utilized for acquiring the U content and 234U/238U activity ratio (AR) data, 0.01–1.4µgL−1 and 1.0–3.5, respectively. These results suggest that the water is circulating in a reducing environment and leaching strata containing minerals with low uranium concentration. A tendency to increasing ARs values following the groundwater flow direction is identified in Manaus city. The AR also increases according to the SW–NE directions: Uarini→Tefé; Manacapuru→Manaus; Presidente Figueiredo→São Sebastião do Uatumã; and Boa Vista do Ramos→Parintins. Such trends are possibly related to several factors, among them the increasing acid character of the waters. The waters analyzed are used for human consumption and the highest dissolved U content is much lower than the maximum established by the World Health Organization. Therefore, in view of this radiological parameter they can be used for drinking purposes. |
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0969-8043 |
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THL @ christoph.kuells @ silva_uranium_2015 |
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140 |
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Author |
Zagana, E.; Külls, C.; Udluft, P. |
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Title |
Der Wasserhaushalt des Aliakmonas |
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Journal Article |
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2000 |
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Vom Wasser |
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94 |
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29-39 |
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THL @ christoph.kuells @ Zagana2000saa |
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34 |
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Orloff, K.G.; Mistry, K.; Charp, P.; Metcalf, S.; Marino, R.; Shelly, T.; Melaro, E.; Donohoe, A.M.; Jones, R.L. |
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Title |
Human exposure to uranium in groundwater |
Type |
Journal Article |
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Year |
2004 |
Publication |
Environmental Research |
Abbreviated Journal |
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Volume |
94 |
Issue |
3 |
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319-326 |
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Keywords |
Groundwater, Human exposure, Uranium, Urine |
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Abstract |
High concentrations of uranium (mean=620μg/L) were detected in water samples collected from private wells in a residential community. Based on isotopic analyses, the source of the uranium contamination appeared to be from naturally occurring geological deposits. In homes where well water concentrations of uranium exceeded the drinking water standard, the residents were advised to use an alternate water source for potable purposes. Several months after the residents had stopped drinking the water, urine samples were collected and tested for uranium. Elevated concentrations of uranium (mean=0.40μg/g creatinine) were detected in urine samples, and 85 percent of the urine uranium concentrations exceeded the 95th percentile concentration of a national reference population. Urine uranium concentrations were positively correlated with water uranium concentrations, but not with the participants’ ages or how long they had been drinking the water. Six months later, a second urine sample was collected and tested for uranium. Urine uranium concentrations decreased in most (63 percent) of the people. In those people with the highest initial urine uranium concentrations, the urine levels decreased an average of 78 percent. However, urine uranium concentrations remained elevated (mean=0.27μg/g), and 87 percent of the urine uranium concentrations exceeded the 95th percentile concentration of the reference population. The results of this investigation demonstrated that after long-term ingestion of uranium in drinking water, elevated concentrations of uranium in urine could be detected up to 10 months after exposure had stopped. |
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0013-9351 |
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THL @ christoph.kuells @ orloff_human_2004 |
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136 |
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