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Lawrinenko, M.; Kurwadkar, S.; Wilkin, R.T. |
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Title |
Long-term performance evaluation of zero-valent iron amended permeable reactive barriers for groundwater remediation – A mechanistic approach |
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Journal Article |
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Year |
2023 |
Publication |
Geoscience Frontiers |
Abbreviated Journal |
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Volume  |
14 |
Issue |
2 |
Pages |
101494 |
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Keywords |
Geochemistry, Iron, Permeable reactive barrier, Plating reactions, Reduction potential, Surface passivation |
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Abstract |
Permeable reactive barriers (PRBs) are used for groundwater remediation at contaminated sites worldwide. This technology has been efficient at appropriate sites for treating organic and inorganic contaminants using zero-valent iron (ZVI) as a reductant and as a reactive material. Continued development of the technology over the years suggests that a robust understanding of PRB performance and the mechanisms involved is still lacking. Conflicting information in the scientific literature downplays the critical role of ZVI corrosion in the remediation of various organic and inorganic pollutants. Additionally, there is a lack of information on how different mechanisms act in tandem to affect ZVI-groundwater systems through time. In this review paper, we describe the underlying mechanisms of PRB performance and remove isolated misconceptions. We discuss the primary mechanisms of ZVI transformation and aging in PRBs and the role of iron corrosion products. We review numerous sites to reinforce our understanding of the interactions between groundwater contaminants and ZVI and the authigenic minerals that form within PRBs. Our findings show that ZVI corrosion products and mineral precipitates play critical roles in the long-term performance of PRBs by influencing the reactivity of ZVI. Pore occlusion by mineral precipitates occurs at the influent side of PRBs and is enhanced by dissolved oxygen and groundwater rich in dissolved solids and high alkalinity, which negatively impacts hydraulic conductivity, allowing contaminants to potentially bypass the treatment zone. Further development of site characterization tools and models is needed to support effective PRB designs for groundwater remediation. |
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1674-9871 |
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THL @ christoph.kuells @ lawrinenko_long-term_2023 |
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143 |
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Author |
Rubin, R. |
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Title |
Water conservation methods in Israel’s Negev desert in late antiquity |
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Journal Article |
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Year |
1988 |
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Journal of Historical Geography |
Abbreviated Journal |
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Volume |
14 |
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3 |
Pages |
229-244 |
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Settlement in Israel’s Negev desert historically has been dependent on water conservation techniques. Fieldwork carried out on settlement sites constructed during the Byzantine period, when agriculture and trade flourished, revealed a variety of water installations some of which are in use today. Perennial springs in the Negev are generally small and difficult of access. Cisterns were the most common conservation devices and came in both large, enclosed and single, open forms. Cisterns were common particularly in the towns, where they were usually built as part of house foundations. Dams were discovered at several sites but proved to be inefficient and easily abandoned because of evaporation and siltation problems. Public reservoirs were part of the structure of the largest towns and were open and among the larges structures uncovered at settlement sites. Wells were distributed widely throughout the desert and were part of the only conservation system that did not depend directly on surface rainfall. A qanat system was located in the eastern Negev dating from the late settlement period before the area was abandoned at the turn of the eighth century. These various water systems raise questions about their builders and their origins, and suggests that builders originating in more humid Mediterranean environments tended to produce less adaptable installations than builders derived from the south or the east. |
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0305-7488 |
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THL @ christoph.kuells @ Rubin1988229 |
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262 |
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Author |
Lach, P.; Cathelineau, M.; Brouand, M.; Fiet, N. |
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Title |
In-situ Isotopic and Chemical Study of Pyrite from Chu-Sarysu (Kazakhstan) Roll-front Uranium Deposit |
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Journal Article |
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Year |
2015 |
Publication |
Procedia Earth and Planetary Science |
Abbreviated Journal |
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13 |
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207-210 |
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LA-ICP-MS, pyrite, roll-front, SIMS, sulfur isotopy, traces elements, uranium |
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Abstract |
Pyrite is common in roll-front type uranium deposit in Chu-sarysu basin, Kazakhstan. Combined in-situ microstructural, isotopic and chemical analysis of pyrite indicates variation in precipitation conditions and in fluid composition. Broad-scale δ34S heterogeneity indicates a complex multi-facet evolution. First generation authigenic framboïdal aggregates are biogenic as demonstrated by the lowest δ34S values of -48‰ to -28‰. The latest generation pyrites are probably hydrothermal with greater δ34S variation (-30‰ to +12‰). This hydrothermal pyrite commonly displays variable enrichment of several trace elements especially As, Co and Ni. Strong variation in δ34S values and variable trace element enrichment is interpreted in terms of continuous variations in fluid composition. |
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1878-5220 |
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THL @ christoph.kuells @ lach_-situ_2015 |
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182 |
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Author |
Akter, A.; Tanim, A.H.; Islam, M.K. |
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Title |
Possibilities of urban flood reduction through distributed-scale rainwater harvesting |
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Journal Article |
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Year |
2020 |
Publication |
Water Science and Engineering |
Abbreviated Journal |
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13 |
Issue |
2 |
Pages |
95-105 |
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Low-impact development (LID), SWMM, HEC-RAS, Remote sensing, Urban flooding, Inundation depth |
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Urban flooding in Chittagong City usually occurs during the monsoon season and a rainwater harvesting (RWH) system can be used as a remedial measure. This study examines the feasibility of rain barrel RWH system at a distributed scale within an urbanized area located in the northwestern part of Chittagong City that experiences flash flooding on a regular basis. For flood modeling, the storm water management model (SWMM) was employed with rain barrel low-impact development (LID) as a flood reduction measure. The Hydrologic Engineering Center’s River Analysis System (HEC-RAS) inundation model was coupled with SWMM to observe the detailed and spatial extent of flood reduction. Compared to SWMM simulated floods, the simulated inundation depth using remote sensing data and the HEC-RAS showed a reasonable match, i.e., the correlation coefficients were found to be 0.70 and 0.98, respectively. Finally, using LID, i.e., RWH, a reduction of 28.66% could be achieved for reducing flood extent. Moreover, the study showed that 10%–60% imperviousness of the subcatchment area can yield a monthly RWH potential of 0.04–0.45 m3 from a square meter of rooftop area. The model can be used for necessary decision making for flood reduction and to establish a distributed RWH system in the study area. |
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1674-2370 |
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THL @ christoph.kuells @ Akter202095 |
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247 |
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Author |
Ubierna, J.A.J. |
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Title |
Tunnel heritage in Spain: Roots of the underground |
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Journal Article |
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Year |
1998 |
Publication |
Tunnelling and Underground Space Technology |
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13 |
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2 |
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131-141 |
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Abstract |
Spain has deep roots in the underground. The territory of myth and legend, of cave and tunnel, has existed in Spain since that ancient time overwhelmed with shreds of fog, where all was myth around heros like Túbal Hércules, Gárgoris and Abidis. The underground evokes strong links with life and death, light and darkness, and has served as a source of inspiration for art through the centuries. The history of tunnels in Spain reflects the mosaic of cultures that have inhabited Iberia from prehistoric times till today. This contribution on the subterranean History of Spain traces the country’s heritage in the form of natural caves, troglodyte dwellings, mining, crypts, galleries in fortresses and castles, aqueducts, qanats, cellars, and other landmarks. |
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0886-7798 |
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THL @ christoph.kuells @ Ubierna1998131 |
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260 |
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Author |
Wilson, G.B.; McNeill, G.W. |
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Title |
Noble gas recharge temperatures and the excess air component |
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Journal Article |
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Year |
1997 |
Publication |
Applied Geochemistry |
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12 |
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6 |
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747-762 |
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The calculation of a groundwater recharge temperature based on the dissolved concentrations of Ne, Ar, Kr and Xe requires a correction for noble gas supersaturation due to excess air entrainment. This entrainment is commonly attributed to the recharge process or to air contamination at the wellhead during sample collection. With the exception of some local studies, most work has concentrated on interpretation of the recharge temperature or quantification of the radiogenic content for palaeoclimatic and dating purposes. The magnitude and source of the excess air is not directly relevant to these studies and so is often ignored. In this work, excess air Ne and other data have been calculated from new and published noble gas data sets for several groundwater systems. For younger groundwaters which have been recharged under one broad climatic regime, the amount of air entrainment increases according to lithology in the order granites, sandstones and limestones respectively. A negative correlation between precipitation and excess air entrainment is identified in at least one aquifer, and some of the mechanisms which may influence the entrainment process are discussed. |
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0883-2927 |
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THL @ christoph.kuells @ Wilson1997747 |
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281 |
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Musy, S.; Meyzonnat, G.; Barbecot, F.; Hunkeler, D.; Sültenfuss, J.; Solomon, D.K.; Purtschert, R. |
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In-situ sampling for krypton-85 groundwater dating |
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Journal Article |
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2021 |
Publication |
Journal of Hydrology X |
Abbreviated Journal |
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11 |
Issue |
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Pages |
100075 |
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Noble gases, Tracers, Groundwater, Dating, Sampling Methodology |
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Krypton-85 and other radioactive noble gases are widely used for groundwater dating purposes. 85Kr analysis require large volumes of water to reach the analytical requirements. Conventionally, this water is pumped to the surface to be degassed with a gas extraction system. The large pumping rate may disturb the natural flow field and requires substantial field logistics. Hence, we propose a new in-situ degassing method, in which membrane contactors are used to degas the groundwater directly in the well and gas is collected at the surface. This way, field work is facilitated, groundwater system disturbance is minimized, and the gas sample is collected at a specific depth. We demonstrate the tightness of the system regarding atmospheric air contamination for a collection times of 24 h, which is sufficient for both low-level counting and laser-based counting methods for 85Kr. The minimal borehole diameter is 7.5 cm for the prototype presented in this research but can easily be reduced to smaller diameters. In a case study, we compare the results obtained with the new passive method with those from a conventional packer setup sampling. Additionally, 3H/3He samples were collected for both sampling regimes and the dating results were compared with those from 85Kr. A good agreement between tracer ages is demonstrated and the age stratigraphy is consistent with the expected age distribution for a porous unconfined aquifer. In addition, our study emphasizes the differences between the age information sampled with various methods. In conclusion, we demonstrate that the new in situ quasi-passive method provides a more representative age stratigraphy with depth in most cases. |
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2589-9155 |
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THL @ christoph.kuells @ Musy2021100075 |
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215 |
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Konapala, G.; Mishra, A.K.; Wada, Y.; Mann, M.E. |
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Title |
Climate change will affect global water availability through compounding changes in seasonal precipitation and evaporation |
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Journal Article |
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2020 |
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Nature Communications |
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11 |
Issue |
1 |
Pages |
3044 |
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Both seasonal and annual mean precipitation and evaporation influence patterns of water availability impacting society and ecosystems. Existing global climate studies rarely consider such patterns from non-parametric statistical standpoint. Here, we employ a non-parametric analysis framework to analyze seasonal hydroclimatic regimes by classifying global land regions into nine regimes using late 20th century precipitation means and seasonality. These regimes are used to assess implications for water availability due to concomitant changes in mean and seasonal precipitation and evaporation changes using CMIP5 model future climate projections. Out of 9 regimes, 4 show increased precipitation variation, while 5 show decreased evaporation variation coupled with increasing mean precipitation and evaporation. Increases in projected seasonal precipitation variation in already highly variable precipitation regimes gives rise to a pattern of “seasonally variable regimes becoming more variable”. Regimes with low seasonality in precipitation, instead, experience increased wet season precipitation. |
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English |
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2041-1723 |
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THL @ christoph.kuells @ Konapala2020 |
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284 |
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Author |
Adolph, G.; KÜlls, C.; Willscheid, A. |
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Determination and validation of age structures as an improved measure of hydrological dynamics |
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Conference Article |
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2007 |
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Geophysical Research Abstracts |
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9 |
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08013 |
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THL @ christoph.kuells @ Adolph2007determination |
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58 |
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Petisco-Ferrero, S.; Idoeta, R.; Rozas, S.; Olondo, C.; Herranz, M. |
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Radiological environmental monitoring of groundwater around NPP: A proposal for its assessment |
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Journal Article |
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2023 |
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Heliyon |
Abbreviated Journal |
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9 |
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9 |
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19470 |
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Detection limit, Nuclear power plant dismantling and decommissioning, Radiological environmental monitoring, Radionuclides in groundwater |
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Whether a nuclear installation has radiological impact and, in that case, its extension, are the questions behind any environmental analysis of the installation along its operational life. This analysis is based on the detailed establishment of the radiological background of the area. Accordingly, the dismantling and decommissioning process (D&D) of a nuclear power plant starts with a radiological monitoring plan, which includes the radiological characterization of the area and of its surroundings. At the completion of the D&D, unrestricted use for the site will be permitted strictly in accordance with results of the radiological survey within the limits established by the local authorities. Groundwater quality is typically included in any radiological analysis since, among other reasons, a significant part of it is highly likely to end up being extracted for domestic use and hence, human consumption. While there is no regulation containing maximum activity concentration or radionuclide guidance values for water that may be destined for uses other than public consumption, if groundwater is considered a “part” of the land, dose criteria for site release can be applied. Therefore, together with the guidance levels to be established for the different radionuclides expected in the groundwater, the detection limits to be employed when performing routine radio analytical characterization procedures in the laboratory should also be provided. In this paper, we first propose a relation of the potential radionuclides to be analyzed in groundwater, together with their detection limits to be achieved when the determinations are performed in a laboratory, and subsequently, we discuss the most suitable analytical methodologies and resources that would be necessary to undertake radiological characterization plans from a practical point of view. |
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2405-8440 |
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THL @ christoph.kuells @ petisco-ferrero_radiological_2023 |
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133 |
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