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Su, X.; Liu, Z.; Yao, Y.; Du, Z. |
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Title |
Petrology, mineralogy, and ore leaching of sandstone-hosted uranium deposits in the Ordos Basin, North China |
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Journal Article |
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2020 |
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Ore Geology Reviews |
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127 |
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103768 |
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Geochemical composition, leach mining, Mineralogy, Ordos Basin, Sandstone-hosted uranium deposit |
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Abstract |
The Nalinggou–Daying uranium metallogenic belt is situated at the northern Ordos Basin, China. Petrographical, mineralogical and geochemical techniques were used to study the ore-bearing sandstones and host rocks in the Nalinggou–Daying uranium metallogenic belt. The present study shows that uranium minerals, i.e., coffinite, pitchblende, and brannerite, are mostly disseminated around pyrite and detrital particles. The ore-bearing sandstones are enriched in organic matter, with which this reductive environment influenced uranium leaching. The carbonate concentration of the uranium ores is markedly higher than that of the host rocks, and intense carbonatization occurs in the ore-bearing sandstones. In this case, the usage of the classical in-situ leach uranium mining technique by injecting H2SO4 + H2O2 solution produces calcium sulfate precipitate, which can lead to blocking of the ore-bearing strata. For this reason, laboratory and field uranium mining tests were conducted using CO2 + O2 in-situ leaching technology and were demonstrated to be successful, illustrating that this approach is technically feasible. Inhibiting ore bed blockage and increasing the amount of injected O2 are important for uranium leaching in this setting. |
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THL @ christoph.kuells @ su_petrology_2020 |
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120 |
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Sahoo, S.K.; Jha, V.N.; Patra, A.C.; Jha, S.K.; Kulkarni, M.S. |
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Title |
Scientific background and methodology adopted on derivation of regulatory limit for uranium in drinking water – A global perspective |
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Journal Article |
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2020 |
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Environmental Advances |
Abbreviated Journal |
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2 |
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100020 |
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Drinking water, Global policy, Regulatory limits, Toxicity, Uranium |
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Guideline values are prescribed for drinking water to ensure long term protection of the public against anticipated potential adverse effects. There is a great public and regulatory agencies interest in the guideline values of uranium due to its complex behavior in natural aquatic system and divergent guideline values across the countries. Wide variability in guideline values of uranium in drinking water may be attributed to toxicity reference point, variation in threshold values, uncertainty within intraspecies and interspecies, resource availability, socio-economic condition, variation in ingestion rate, etc. Although guideline values vary to a great extent, reasonable scientific basis and technical judgments are essential before it could be implemented. Globally guideline values are derived considering its radiological or chemical toxicity. Minimal or no adverse effect criterions are normally chosen as the basis for deriving the guideline values of uranium. In India, the drinking water limit of 60 µg/L has been estimated on the premise of its radiological concern. A guideline concentration of 2 µg/L is recommended in Japan while 1700 µg/L in Russia. The relative merit of different experimental assumption, scientific approach and its methodology adopted for derivation of guideline value of uranium in drinking water in India and other countries is discussed in the paper. |
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THL @ christoph.kuells @ sahoo_scientific_2020 |
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127 |
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Lartigue, J.E.; Charrasse, B.; Reile, B.; Descostes, M. |
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Title |
Aqueous inorganic uranium speciation in European stream waters from the FOREGS dataset using geochemical modelling and determination of a U bioavailability baseline |
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Journal Article |
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Year |
2020 |
Publication |
Chemosphere |
Abbreviated Journal |
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Volume |
251 |
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126302 |
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Bioavailable fraction, Geochemical mapping / baseline, Modelling, Speciation, Stream water, Uranium |
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The concentration of the bioavailable uranium fraction (Ubio) at the European scale was deduced by geochemical modelling considering several definitions found in the literature and the FOREGS European stream waters geochemical atlas dataset to produce a Ubio baseline. A sensitivity analysis was performed using three thermodynamic databases. We also investigated the link between total dissolved uranium (Uaq) concentrations, speciation and global stream water chemistry on the one hand, and the lithology and ages of the surrounding rocks on the other. The more U-enriched the stream sediments or rock type contexts are, which tends to be the case with rocks containing silicates (4.1 mg/kg), the less U-concentrated the stream waters are (0.15 μg/L). Sedimentary rocks lead to slightly higher Uaq concentrations (0.34 μg/L) even if the concentration in sediment (Used) is relatively low (1.6 mg/kg). This trend is reversed for Ubio, with higher concentrations in a crystalline context. The mean estimated Ubio value ranges from 1.5.10−3 to 65.3 ng/L and can fluctuate by 3 orders of magnitude depending on the considered definition as opposed to by 2 orders of magnitude accountable to differences between thermodynamic databases. The classification of the water in relation to the two surrounding rock lithologies makes it possible to reduce the mean variability for the Ubio concentrations. Irrespective of the definition of Ubio considered, in 59% of cases the Ubio fraction represents less than 1% of Uaq. Several threshold values relating to Ubio were proposed, assuming knowledge only of the aqueous concentrations of the major elements and Uaq. |
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0045-6535 |
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THL @ christoph.kuells @ lartigue_aqueous_2020 |
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141 |
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Pree, T.A.D. |
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Title |
The politics of baselining in the Grants uranium mining district of northwestern New Mexico |
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Journal Article |
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Year |
2020 |
Publication |
Journal of Environmental Management |
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268 |
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Pages |
110601 |
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Critical stakeholder analysis, Environmental cleanup, Environmental monitoring, Mining reclamation/remediation/restoration, Politics of baselining |
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During the second half of the twentieth century, northwestern New Mexico served as the primary production site for one of the world’s largest nuclear arsenals. From 1948 to 1970 the “Grants uranium district” provided almost half of the total uranium ore accumulated by the United States federal government for the production of nuclear weapons, in addition to becoming a national source for commercial nuclear energy from the late 1960s to the early 1990s. By the twenty-first century, after a prolonged period of economic decline that began in the late 1970s, all uranium mining and milling in New Mexico had ceased, leaving a legacy of environmental health impacts. What was once referred to as “The Uranium Capital of the World” now encompasses over a thousand abandoned uranium mines and seven massive uranium mill tailings piles, which are associated with airborne and soil contamination as well as groundwater plumes of uranium and other contaminants of concern, in a landscape that has been fractured by underground mine workings and punctured by thousands of exploratory boreholes. This article presents an ethnographic study of the diverse forms of expertise involved in monitoring and managing the mine waste and mill tailings. Drawing from over two years of ethnographic research, I describe the relationship between different stakeholders from local communities, government agencies, and transnational mining corporations as they deliberate about the possibility of cleaning up the former mining district. My thesis is that the possibility of cleaning up the Grants district hinges on the “politics of baselining”—a term I introduce to describe the relationship between stakeholders and their competing environmental models and hydrogeological theories; each accounts for a different geological past prior to mining that can be deemed “natural,” as the background against which to measure the anthropogenic impacts from mining. |
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0301-4797 |
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THL @ christoph.kuells @ pree_politics_2020 |
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151 |
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Gardiner, J.; Thomas, R.B.; Phan, T.T.; Stuckman, M.; Wang, J.; Small, M.; Lopano, C.; Hakala, J.A. |
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Title |
Utilization of produced water baseline as a groundwater monitoring tool at a CO2-EOR site in the Permian Basin, Texas, USA |
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Journal Article |
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2020 |
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Applied Geochemistry |
Abbreviated Journal |
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121 |
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104688 |
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CO storage, Enhanced oil recovery, Geochemical baseline, Groundwater monitoring, Produced water, Solubility trapping |
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Carbon dioxide (CO2) enhanced oil recovery (EOR) provides a pathway for economic reuse and storage of CO2, a greenhouse gas. One challenge with this practice is ensuring CO2 injection does not result in target reservoir fluids migrating into overlying shallow (\textless1000 m) groundwater formations. Effective monitoring for leakage from storage formations could involve measuring sensitive chemical indicators in overlying groundwater units and within the producing formation itself for evidence of deviation from an initial state. In this study, produced waters and overlying groundwaters were monitored over a five-year period to evaluate which geochemical signals may be useful to ensure that oilfield produced waters did not impact overlying groundwaters. During this five-year period, a mature carbonate oil reservoir in the Permian Basin transitioned from a waterflooding operation to a water-alternating-gas injection (WAG), in which the formation was flooded with CO2 and various mixtures of produced water. Significant increases in dissolved inorganic constituents [alkalinity, TDS, Na+, Cl−, SO42−] were observed in produced waters following CO2 injection; however, carbonate reservoir dissolution-precipitation reactions appear to be minimal and injected CO2 appears to be stored via solubility trapping. Although there are statistically significant geochemical variations following CO2 injection, applying isometric log-ratios to certain parameters establishes a narrow range for post-CO2 injection produced waters. This narrow range can be considered a baseline for post-CO2 injection produced waters; this baseline can be utilized to monitor overlying local groundwaters for produced water intrusion. Additionally, certain parameters [Na+, Ca2+, K+, Cl−, alkalinity, and TDS] display large concentration disparities between produced water and overlying groundwaters; these parameters would be sensitive indicators of produced water intrusion into overlying groundwaters. |
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0883-2927 |
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THL @ christoph.kuells @ gardiner_utilization_2020 |
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171 |
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Jroundi, F.; Descostes, M.; Povedano-Priego, C.; Sánchez-Castro, I.; Suvannagan, V.; Grizard, P.; Merroun, M.L. |
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Profiling native aquifer bacteria in a uranium roll-front deposit and their role in biogeochemical cycle dynamics: Insights regarding in situ recovery mining |
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Journal Article |
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Year |
2020 |
Publication |
Science of The Total Environment |
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721 |
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137758 |
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Bacterial diversity, Bioremediation, In-situ recovery, Natural attenuation, Network analysis, Uranium |
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Abstract |
A uranium-mineralized sandy aquifer, planned for mining by means of uranium in situ recovery (U ISR), harbors a reservoir of bacterial life that may influence the biogeochemical cycles surrounding uranium roll-front deposits. Since microorganisms play an important role at all stages of U ISR, a better knowledge of the resident bacteria before any ISR actuations is essential to face environmental quality assessment. The focus here was on the characterization of bacteria residing in an aquifer surrounding a uranium roll-front deposit that forms part of an ISR facility project at Zoovch Ovoo (Mongolia). Water samples were collected following the natural redox zonation inherited in the native aquifer, including the mineralized orebody, as well as compartments located both upstream (oxidized waters) and downstream (reduced waters) of this area. An imposed chemical zonation for all sensitive redox elements through the roll-front system was observed. In addition, high-throughput sequencing data showed that the bacterial community structure was shaped by the redox gradient and oxygen availability. Several interesting bacteria were identified, including sulphate-reducing (e.g. Desulfovibrio, Nitrospira), iron-reducing (e.g. Gallionella, Sideroxydans), iron-oxidizing (e.g. Rhodobacter, Albidiferax, Ferribacterium), and nitrate-reducing bacteria (e.g. Pseudomonas, Aquabacterium), which may also be involved in metal reduction (e.g. Desulfovibrio, Ferribacterium, Pseudomonas, Albidiferax, Caulobacter, Zooglea). Canonical correspondence analysis (CCA) and co-occurrence patterns confirmed strong correlations among the bacterial genera, suggesting either shared/preferred environmental conditions or the performance of similar/complementary functions. As a whole, the bacterial community residing in each aquifer compartment would appear to define an ecologically functional ecosystem, containing suitable microorganisms (e.g. acidophilic bacteria) prone to promote the remediation of the acidified aquifer by natural attenuation. Assessing the composition and structure of the aquifer’s native bacteria is a prerequisite for understanding natural attenuation and predicting the role of bacterial input in improving ISR efficiency. |
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0048-9697 |
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THL @ christoph.kuells @ jroundi_profiling_2020 |
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177 |
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Robin, V.; Beaufort, D.; Tertre, E.; Reinholdt, M.; Fromaget, M.; Forestier, S.; Boissezon, H. de; Descostes, M. |
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Fate of dioctahedral smectites in uranium roll front deposits exploited by acidic In Situ Recovery (ISR) solutions |
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Journal Article |
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Year |
2020 |
Publication |
Applied Clay Science |
Abbreviated Journal |
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187 |
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Pages |
105484 |
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Dissolution, In situ recovery, Ion exchange, Post mining, Remediation, Smectite |
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In Situ Recovery (ISR) is the most important process of uranium production in the world (50%). It consists of an injection of a leaching solution into a permeable mineralized aquifer (sandstone), pumping of the solution after dissolution of the ore minerals and recovery of the uranium from the pregnant solution in a surface plant. In this context, the fate of swelling clay minerals such as smectites is of main importance due to their role in the mobility of cationic elements by diverse geochemical processes such as ion-exchange reactions or dissolution. The present study details analysis of dioctahedral smectites before and after in-situ leaching by acidic (H2SO4) ISR solutions. Samples were collected from two sedimentary basins hosting some of the main uranium roll front deposits exploited by acidic ISR (Tortkuduk deposit, Shu-Saryssu basin, Kazakhstan, and Dulaan Uul and Zoovch Ovoo deposits, Sainshand basin, Mongolia). Scanning Electron Microscope and X-Ray Diffraction analysis revealed that dioctahedral smectite is a ubiquitous mineral in all analyzed samples, before and after acidification, and revealed a difference of crystal chemistry of the smectites between deposits of Kazakhstan (beidellite type) and Mongolia (montmorillonite type). Chemical analysis and semi-quantification of the smectites before and after acidification also revealed a difference in chemical reactivity, with a higher dissolution of montmorillonite layers compared to beidellite ones, and the importance of ion-exchange reactions. These findings are consistent with literature data obtained on model systems. The persistence of dioctahedral smectites after several years of acidification is crucial for the understanding of geochemical processes during uranium production or remediation of the aquifers. Finally, based on the analysis of samples from U-deposits hosted in both sedimentary basins, a schematic model of the impact of acid solutions on dioctahedral smectite was proposed. |
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0169-1317 |
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THL @ christoph.kuells @ robin_fate_2020 |
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179 |
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Bonnetti, C.; Zhou, L.; Riegler, T.; Brugger, J.; Fairclough, M. |
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Large S isotope and trace element fractionations in pyrite of uranium roll front systems result from internally-driven biogeochemical cycle |
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Journal Article |
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2020 |
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Geochimica et Cosmochimica Acta |
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282 |
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113-132 |
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Activity cycle, Pyrite composition, Roll front uranium deposits, S isotope and trace element fractionation |
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Complex pyrite textures associated with large changes in isotopic and trace element compositions are routinely assumed to be indicative of multi-faceted processes involving multiple fluid and sulfur sources. We propose that the features of ore-stage pyrite from roll front deposits across the world, revealed in exquisite detail via high-resolution trace element mapping by LA-ICP-MS, reflect the dynamic internal evolution of the biogeochemical processes responsible for sulfate reduction, rather than externally driven changes in fluid or sulfur sources through time. Upon percolation of oxidizing fluids into the reduced host-sandstones, roll front systems become self-organized, with a systematic reset of their activity cycle after each translation stage of the redox interface down dip of the aquifer. Dominantly reducing conditions at the redox interface favor the formation of biogenic framboidal pyrite (δ34S from −30.5 to −12.5‰) by bacterial sulfate reduction and the genesis of the U mineralization. As the oxidation front advances, oxidation of reduced sulfur minerals induces an increased supply of sulfate and metals in solution to the bacterial sulfate reduction zone that has similarly advanced down the flow gradient. Hence, this stage is marked by increased rates of the bacterial sulfate reduction associated with the crystallization of variably As-Co-Ni-Mo-enriched concentric pyrite (up to 10,000′s of ppm total trace contents) with moderately negative δ34S values (from −13.7 to −7.5‰). A final stage of pyrite cement with low trace element contents and heavier δ34S signature (from −6.9 to +18.8‰) marks the end of the roll front activity cycle and the transition from an open to a predominantly closed system behavior (negligible advection of fresh sulfate). Blocky pyrite cement is formed using the remaining sulfate, which now becomes quickly heavy according to a Rayleigh isotope fractionation process. This ends the cycle by depleting the nutrient supplies for the sulfate-reducing bacteria and cementing pore spaces within the host sandstone, effectively restricting fluid infiltration. This internally-driven roll front activity cycle results in systematic, large S isotope and trace element fractionation. Ultimately, the long-time evolution of the basin and fluid sources control the metal endowment and evolution of the system; these events, however, are unlikely to be preserved by the roll front, as a direct result of its hydrodynamic nature. |
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0016-7037 |
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THL @ christoph.kuells @ bonnetti_large_2020 |
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185 |
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Zhou, Y.; Li, G.; Xu, L.; Liu, J.; Sun, Z.; Shi, W. |
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Uranium recovery from sandstone-type uranium deposit by acid in-situ leaching – an example from the Kujieertai |
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Journal Article |
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2020 |
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Hydrometallurgy |
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191 |
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105209 |
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Acid in-situ leaching, Sandstone-type uranium deposit, Uranium deportment in the ore, Uranium recovery, Water-rock interaction |
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The factors influencing uranium recovery in water-rock systems during acid in-situ leaching (ISL) were studied at the Kujieertai uranium deposit in Xinjiang. Using an ISL unit, a field leach trial (FLT) had been carried out to test the sequential effects of a leaching solution without oxidant (H2SO4 solution 4–8 g/L) and a leaching solution with oxidant (H2SO4 3–7 g/L, and Fe (III) 2–6 g/L). The observation of the leaching process revealed clearly defined stages of uranium release from the solid mineral to solution. Uranium mobilization from solid mineral into solution can be described in four stages. At the beginning of the acid ISL process, there was no oxidant to be added to the leaching solution and the desorption of hexavalent uranyl ions in the open pores, as well as dissolution of hexavalent uranium minerals, led to a short-term peak in the pregnant solution, which happened while pH decreased from about 5.3 to 2.62. Following the depletion of the adsorbed hexavalent uranium and a decline in uranium dissolution intensity, the addition of Fe(III) facilitated the oxidation of tetravalent uranium, which enabled intensive uranium mobilization again. During this process, the dissolution of uranium had a strong positive correlation with the reduction of Fe(III) and Eh in the leach solution. Beside hydrochemical factors, the deportment of uranium was also an important factor affecting uranium recovery. Uranium located in the open pores can be completely exposed to the solution and the mobilization intensity was significantly affected by hydrogeochemical conditions; but the uranium present in microfissures and in the ore matrix could not be fully exposed to the solution, so, their dissolution intensity was primarily controlled by corrosion and permeability of the ore. In general, the hydrogeochemical conditions and the deportment of uranium were the external and internal factors that significantly affected the dissolution and recovery of uranium in the early and middle stages of the FLT. However, in the latest stages, due to uranium depletion, enhancing the chemical potential of the leaching solution, specifically acidity and/or the amount of oxidant, had little improvement on uranium recovery. |
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0304-386x |
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THL @ christoph.kuells @ zhou_uranium_2020 |
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205 |
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Gil-Márquez, J.M.; Sültenfuß, J.; Andreo, B.; Mudarra, M. |
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Title |
Groundwater dating tools (3H, 3He, 4He, CFC-12, SF6) coupled with hydrochemistry to evaluate the hydrogeological functioning of complex evaporite-karst settings |
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Journal Article |
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2020 |
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Journal of Hydrology |
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580 |
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124263 |
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Keywords |
Groundwater dating, Evaporite karst, Brine spring, Free-shape models |
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Abstract |
The hydrogeological functioning of four different areas in a complex evaporite-karst unit of predominantly aquitard behavior in S Spain was investigated. Environmental dating tracers (3H, 3He, 4He, CFC-12, SF6) and hydrochemical data were determined from spring samples to identify and characterize groundwater flow components of different residence times in the media. Results show a general geochemical evolution pattern, from higher (recharge areas) to lower positions (discharge areas), in which mineralization rises as well as the value of the rCl−/SO42−, evidencing longer water-rock interaction. Ne values show degassing of most of the samples, favored by the high salinity of groundwater and the development of karstification so that the concentration of all the considered gases were corrected according to the difference between the theoretical and the measured Ne. The presence of modern groundwater in every sample was proved by the detection of 3H and CFC-12. At the opposite, the higher amount of radiogenic 4He in most samples also indicates that they have an old component. The 3H/3He dating method does not give reliable ages as a consequence of degassing and the large uncertainty of the 3He/4He ratios of the sources for the radiogenic Helium. The large SF6 concentrations suggest terrigenic production related to halite and dolomite. Binary Mixing and Free Shape Models were created based on 3H and CFC-12 data to interpret the age distribution of the samples. Two parameters (GA50 and >70%) were proposed as an indicator of that distribution, as they provide further information than the mean age. Particularly, GA50 is derived from the median groundwater age and is presented as a new way of interpreting mixed groundwater age data. A greater fraction of old groundwater (3H and CFC-12 free) was identified in discharge areas, while the proportion and estimated infiltration date of the younger fractions in recharge areas were higher and more recent, respectively. The application of different approaches has been useful to corroborate previous theoretical conceptual model proposed for the study area and to test the applicability of the used environmental tracer in dating brine groundwater and karst springs. |
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0022-1694 |
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THL @ christoph.kuells @ Gilmarquez2020124263 |
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213 |
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