| Records |
| Author |
Robin, V.; Beaufort, D.; Tertre, E.; Reinholdt, M.; Fromaget, M.; Forestier, S.; Boissezon, H. de; Descostes, M. |
| Title |
Fate of dioctahedral smectites in uranium roll front deposits exploited by acidic In Situ Recovery (ISR) solutions |
Type |
Journal Article |
| Year |
2020 |
Publication  |
Applied Clay Science |
Abbreviated Journal |
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| Volume |
187 |
Issue |
|
Pages |
105484 |
| Keywords |
Dissolution, In situ recovery, Ion exchange, Post mining, Remediation, Smectite |
| Abstract |
In Situ Recovery (ISR) is the most important process of uranium production in the world (50%). It consists of an injection of a leaching solution into a permeable mineralized aquifer (sandstone), pumping of the solution after dissolution of the ore minerals and recovery of the uranium from the pregnant solution in a surface plant. In this context, the fate of swelling clay minerals such as smectites is of main importance due to their role in the mobility of cationic elements by diverse geochemical processes such as ion-exchange reactions or dissolution. The present study details analysis of dioctahedral smectites before and after in-situ leaching by acidic (H2SO4) ISR solutions. Samples were collected from two sedimentary basins hosting some of the main uranium roll front deposits exploited by acidic ISR (Tortkuduk deposit, Shu-Saryssu basin, Kazakhstan, and Dulaan Uul and Zoovch Ovoo deposits, Sainshand basin, Mongolia). Scanning Electron Microscope and X-Ray Diffraction analysis revealed that dioctahedral smectite is a ubiquitous mineral in all analyzed samples, before and after acidification, and revealed a difference of crystal chemistry of the smectites between deposits of Kazakhstan (beidellite type) and Mongolia (montmorillonite type). Chemical analysis and semi-quantification of the smectites before and after acidification also revealed a difference in chemical reactivity, with a higher dissolution of montmorillonite layers compared to beidellite ones, and the importance of ion-exchange reactions. These findings are consistent with literature data obtained on model systems. The persistence of dioctahedral smectites after several years of acidification is crucial for the understanding of geochemical processes during uranium production or remediation of the aquifers. Finally, based on the analysis of samples from U-deposits hosted in both sedimentary basins, a schematic model of the impact of acid solutions on dioctahedral smectite was proposed. |
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| ISSN |
0169-1317 |
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no |
| Call Number |
THL @ christoph.kuells @ robin_fate_2020 |
Serial |
179 |
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| Author |
Christofi, C.; Bruggeman, A.; Külls, C.; Constantinou, C. |
| Title |
Hydrochemical evolution of groundwater in gabbro of the Troodos Fractured Aquifer. A comprehensive approach |
Type |
Journal Article |
| Year |
2020 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
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| Volume |
114 |
Issue |
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Pages |
104524 |
| Keywords |
geochemistry |
| Abstract |
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Thesis |
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| Publisher |
Pergamon |
Place of Publication |
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Editor |
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| Language |
English |
Summary Language |
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no |
| Call Number |
THL @ christoph.kuells @ Christofi2020hydrochemical |
Serial |
13 |
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| Author |
Christofi, C.; Bruggeman, A.; Külls, C.; Constantinou, C. |
| Title |
Isotope hydrology and hydrogeochemical modeling of Troodos Fractured Aquifer, Cyprus: The development of hydrogeological descriptions of observed water types |
Type |
Journal Article |
| Year |
2020 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
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| Volume |
123 |
Issue |
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Pages |
104780 |
| Keywords |
Isotope hydrology, Hydrogeochemical modelling, Hydrochemistry, Kargiotis, Troodos |
| Abstract |
The origin of groundwater recharge and subsequent flow paths are often difficult to establish in fractured, multi-lithological, and highly compartmentalized aquifers such as the Troodos Fractured Aquifer (TFA). As the conjunctive use of stable isotopes and hydrogeochemical data provides additional information, we established a monitoring network for stable isotopes in precipitation in Cyprus. The local meteoric water line, altitude effect and seasonal variation of stable isotopes in precipitation are derived from monitoring data. Stable isotopes and hydrogeochemical data are combined to model water-rock interactions and groundwater evolution along a complete ophiolite sequence. As a result a generic hydrogeologic description for the observed water types is developed. Isotope hydrology was applied in conjunction with hydrogeochemical modelling in Kargiotis Watershed, a major north-south transect of the TFA. PHREEQC was used for hydrogeochemical modelling to establish generic descriptions for observed water types. Mean precipitation-weighted values from 16 monitoring stations were used to calculate the Local Meteoric Water Line (LMWL), which was found to be equal to δ2H = (6.58 ± 0.13)*δ18O + (12.64 ± 0.91). A general decrease of 1.22‰ for δ2H and 0.20‰ for δ18O in precipitation was calculated per 100 m altitude. A generic groundwater evolution path was established: 1. Na/MgClHCO3, 2. MgHCO3, 3. Ca/MgHCO3, 4. Ca/MgNaHCO3, 4a. MgNa/CaHCO3/Cl, 5. NaMg/CaHCO3/Cl, 6. NaHCO3, 7. Na/MgHCO3SO4, 8. NaSO4Cl/HCO3. Hydrogeologic descriptions, consisting of groundwater origin, flow path and possible active water-rock processes, have been realised for the observed water types. The first two water types occur in serpentine and ultramafic-gabbro springs. Type 3 waters represent early stages of recharge and/or short flow paths, in gabbro whereas types 4 and 5 are typical for further percolating waters in gabbro and diabase. Water types 6 and 7 occur both in diabase and in the basal group and represent the regional flow. Water type 8 is the end member of regional, upwelling groundwater in the basal group. The presented descriptions and methods have practical applications in groundwater exploration, characterization, and protection. The methodology can be applied in other complex aquifer systems. |
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english |
Summary Language |
english |
Original Title |
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Series Title |
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Series Issue |
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Edition |
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| ISSN |
0883-2927 |
ISBN |
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Medium |
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| Area |
Cyprus |
Expedition |
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Conference |
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| Notes |
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Approved |
no |
| Call Number |
THL @ christoph.kuells @ Christofi2020104780 |
Serial |
76 |
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| Author |
Gardiner, J.; Thomas, R.B.; Phan, T.T.; Stuckman, M.; Wang, J.; Small, M.; Lopano, C.; Hakala, J.A. |
| Title |
Utilization of produced water baseline as a groundwater monitoring tool at a CO2-EOR site in the Permian Basin, Texas, USA |
Type |
Journal Article |
| Year |
2020 |
Publication |
Applied Geochemistry |
Abbreviated Journal |
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| Volume |
121 |
Issue |
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Pages |
104688 |
| Keywords |
CO storage, Enhanced oil recovery, Geochemical baseline, Groundwater monitoring, Produced water, Solubility trapping |
| Abstract |
Carbon dioxide (CO2) enhanced oil recovery (EOR) provides a pathway for economic reuse and storage of CO2, a greenhouse gas. One challenge with this practice is ensuring CO2 injection does not result in target reservoir fluids migrating into overlying shallow (\textless1000 m) groundwater formations. Effective monitoring for leakage from storage formations could involve measuring sensitive chemical indicators in overlying groundwater units and within the producing formation itself for evidence of deviation from an initial state. In this study, produced waters and overlying groundwaters were monitored over a five-year period to evaluate which geochemical signals may be useful to ensure that oilfield produced waters did not impact overlying groundwaters. During this five-year period, a mature carbonate oil reservoir in the Permian Basin transitioned from a waterflooding operation to a water-alternating-gas injection (WAG), in which the formation was flooded with CO2 and various mixtures of produced water. Significant increases in dissolved inorganic constituents [alkalinity, TDS, Na+, Cl−, SO42−] were observed in produced waters following CO2 injection; however, carbonate reservoir dissolution-precipitation reactions appear to be minimal and injected CO2 appears to be stored via solubility trapping. Although there are statistically significant geochemical variations following CO2 injection, applying isometric log-ratios to certain parameters establishes a narrow range for post-CO2 injection produced waters. This narrow range can be considered a baseline for post-CO2 injection produced waters; this baseline can be utilized to monitor overlying local groundwaters for produced water intrusion. Additionally, certain parameters [Na+, Ca2+, K+, Cl−, alkalinity, and TDS] display large concentration disparities between produced water and overlying groundwaters; these parameters would be sensitive indicators of produced water intrusion into overlying groundwaters. |
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0883-2927 |
ISBN |
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Approved |
no |
| Call Number |
THL @ christoph.kuells @ gardiner_utilization_2020 |
Serial |
171 |
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| Author |
Lartigue, J.E.; Charrasse, B.; Reile, B.; Descostes, M. |
| Title |
Aqueous inorganic uranium speciation in European stream waters from the FOREGS dataset using geochemical modelling and determination of a U bioavailability baseline |
Type |
Journal Article |
| Year |
2020 |
Publication |
Chemosphere |
Abbreviated Journal |
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| Volume |
251 |
Issue |
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Pages |
126302 |
| Keywords |
Bioavailable fraction, Geochemical mapping / baseline, Modelling, Speciation, Stream water, Uranium |
| Abstract |
The concentration of the bioavailable uranium fraction (Ubio) at the European scale was deduced by geochemical modelling considering several definitions found in the literature and the FOREGS European stream waters geochemical atlas dataset to produce a Ubio baseline. A sensitivity analysis was performed using three thermodynamic databases. We also investigated the link between total dissolved uranium (Uaq) concentrations, speciation and global stream water chemistry on the one hand, and the lithology and ages of the surrounding rocks on the other. The more U-enriched the stream sediments or rock type contexts are, which tends to be the case with rocks containing silicates (4.1 mg/kg), the less U-concentrated the stream waters are (0.15 μg/L). Sedimentary rocks lead to slightly higher Uaq concentrations (0.34 μg/L) even if the concentration in sediment (Used) is relatively low (1.6 mg/kg). This trend is reversed for Ubio, with higher concentrations in a crystalline context. The mean estimated Ubio value ranges from 1.5.10−3 to 65.3 ng/L and can fluctuate by 3 orders of magnitude depending on the considered definition as opposed to by 2 orders of magnitude accountable to differences between thermodynamic databases. The classification of the water in relation to the two surrounding rock lithologies makes it possible to reduce the mean variability for the Ubio concentrations. Irrespective of the definition of Ubio considered, in 59% of cases the Ubio fraction represents less than 1% of Uaq. Several threshold values relating to Ubio were proposed, assuming knowledge only of the aqueous concentrations of the major elements and Uaq. |
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0045-6535 |
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no |
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THL @ christoph.kuells @ lartigue_aqueous_2020 |
Serial |
141 |
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| Author |
Jin, Z.; Külls, C. |
| Title |
FDM based OA-ICOS for high accuracy 13C quantification in gaseous CO2 |
Type |
Journal Article |
| Year |
2020 |
Publication |
Earth and Environmental Science |
Abbreviated Journal |
EES |
| Volume |
446 |
Issue |
3 |
Pages |
032061 |
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IOP Conference Series |
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no |
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THL @ christoph.kuells @ Jin2020fdm |
Serial |
16 |
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| Author |
Krüger, N.; Külls, C.; Bruggeman, A.; Eliades, M.; Christophi, C.; Rigas, M.; Eracleous, T. |
| Title |
Groundwater recharge estimates with soil isotope profiles-is there a bias on coarse-grained hillslopes? |
Type |
Conference Article |
| Year |
2020 |
Publication |
EGU General Assembly Conference Abstracts |
Abbreviated Journal |
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Issue |
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Pages |
9840 |
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no |
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THL @ christoph.kuells @ Krueger2020groundwater |
Serial |
42 |
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| Author |
Tziritis, E.; Aschonitis, V.; Balacco, G.; Daras, P.; Doulgeris, C.; Fidelibus, M.D.; Gaubi, E.; Gueddari, M.; Güler, C.; Hamzaoui, F.; others |
| Title |
MEDSAL Project-Salinization of critical groundwater reserves in coastal Mediterranean areas: Identification, risk assessment and sustainable management with the use of integrated modelling and smart ICT tools |
Type |
Conference Article |
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2020 |
Publication |
EGU General Assembly Conference Abstracts |
Abbreviated Journal |
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Issue |
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Pages |
2326 |
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THL @ christoph.kuells @ Tziritis2020medsal |
Serial |
43 |
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Doulgeris, C.; Tziritis, E.; Pisinaras, V.; Panagopoulos, A.; Külls, C. |
| Title |
Prediction of seawater intrusion to coastal aquifers based on non-dimensional diagrams |
Type |
Conference Article |
| Year |
2020 |
Publication |
EGU Geophysical Abstracts |
Abbreviated Journal |
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Issue |
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Pages |
4073 |
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THL @ christoph.kuells @ Doulgeris2020prediction |
Serial |
41 |
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| Author |
Sahoo, S.K.; Jha, V.N.; Patra, A.C.; Jha, S.K.; Kulkarni, M.S. |
| Title |
Scientific background and methodology adopted on derivation of regulatory limit for uranium in drinking water – A global perspective |
Type |
Journal Article |
| Year |
2020 |
Publication |
Environmental Advances |
Abbreviated Journal |
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| Volume |
2 |
Issue |
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Pages |
100020 |
| Keywords |
Drinking water, Global policy, Regulatory limits, Toxicity, Uranium |
| Abstract |
Guideline values are prescribed for drinking water to ensure long term protection of the public against anticipated potential adverse effects. There is a great public and regulatory agencies interest in the guideline values of uranium due to its complex behavior in natural aquatic system and divergent guideline values across the countries. Wide variability in guideline values of uranium in drinking water may be attributed to toxicity reference point, variation in threshold values, uncertainty within intraspecies and interspecies, resource availability, socio-economic condition, variation in ingestion rate, etc. Although guideline values vary to a great extent, reasonable scientific basis and technical judgments are essential before it could be implemented. Globally guideline values are derived considering its radiological or chemical toxicity. Minimal or no adverse effect criterions are normally chosen as the basis for deriving the guideline values of uranium. In India, the drinking water limit of 60 µg/L has been estimated on the premise of its radiological concern. A guideline concentration of 2 µg/L is recommended in Japan while 1700 µg/L in Russia. The relative merit of different experimental assumption, scientific approach and its methodology adopted for derivation of guideline value of uranium in drinking water in India and other countries is discussed in the paper. |
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Edition |
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2666-7657 |
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Approved |
no |
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THL @ christoph.kuells @ sahoo_scientific_2020 |
Serial |
127 |
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