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Author Benites Lazaro, L.L.; Bellezoni, R.; Puppim de Oliveira, J.; Jacobi, P.R.; Giatti, L. doi  openurl
  Title Ten Years of Research on the Water-Energy-Food Nexus: An Analysis of Topics Evolution Type Journal Article
  Year 2022 Publication Frontiers in Water Abbreviated Journal  
  Volume 4 Issue Pages  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ article Serial 86  
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Author Chen, Y.; Hong, Y.; Huang, D.; Dai, X.; Zhang, M.; Liu, Y.; Xu, Z. url  openurl
  Title Risk assessment management and emergency plan for uranium tailings pond Type Journal Article
  Year 2022 Publication Journal of Radiation Research and Applied Sciences Abbreviated Journal  
  Volume 15 Issue 3 Pages 83-90  
  Keywords Emergency management, Interpreted structural model (ISM), Resilience, Risk coupling, Uranium tailings pond  
  Abstract The safety of uranium tailings pond is closely related to social stability and economic development, so it is necessary to improve the emergency management of uranium tailings pond to ensure its safety by adjusting the emergency plan. The Interpretive Structural Model (ISM) is used to analyze the structural relationship between the main risk factors leading to the occurrence of emergencies. The results show that attention should be paid to the risk factors originating from humans and infrastructures, and effective management measures should be adopted in the process of emergency management, for example, people build tighter employee access system, clarify the responsibilities of employees at all levels, and improve monitoring and organizational means. According to the results of ISM analysis, a structural risk control system can be constructed, and a defensive barrier that can effectively block the risk coupling transmission can be designed to prevent the risk from being transformed into an event. For other risks, system resilience management should be strengthened to respond to risks. The process is set as emergency response and accident response. Different management objects use different management methods to make emergency management work efficiently.  
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  Series Volume Series Issue Edition  
  ISSN 1687-8507 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ chen_risk_2022 Serial 128  
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Author French, K. url  openurl
  Title Indigenous knowledge, water management, and learning from our collective past Type Journal Article
  Year 2022 Publication Journal of Anthropological Archaeology Abbreviated Journal  
  Volume 68 Issue Pages 101466  
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  ISSN 0278-4165 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ French2022101466 Serial 253  
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Author Grozeva, N.G.; Radwan, J.; Beaucaire, C.; Descostes, M. url  openurl
  Title Reactive transport modeling of U and Ra mobility in roll-front uranium deposits: Parameters influencing 226Ra/238U disequilibria Type Journal Article
  Year 2022 Publication Journal of Geochemical Exploration Abbreviated Journal  
  Volume 236 Issue Pages 106961  
  Keywords Ra/U, Radioactive disequilibria, Radium, Reactive transport modeling, Roll-front uranium deposit  
  Abstract Uranium reserve estimates in ore deposits can be significantly impacted by 226Ra/238U disequilibria arising from the differential mobility of uranium and radium during groundwater transport. 1D reactive transport models were developed to investigate the long-term effects of retention processes (UO2(am) precipitation, U(VI) and Ra sorption on smectite, Ra co-precipitation with barite) on the repartitioning of 238U and 226Ra during formation of roll-front type deposits. Analytical solutions to radioactive decay chains were used in complement to examine the influence of geochemical parameters, including fluid 234U/238U activity ratios and α-recoil loss, on 226Ra/238U disequilibria in uranium ores. Model results demonstrate that smectite and barite can produce 226Ra/238U ratios \textgreater1 at low uranium contents and may explain 226Ra/238U disequilibria occurring in altered rock up- and downstream of roll-front deposits. The capacity of these phases to take up Ra and generate 226Ra/238U disequilibria depends on both mineral contents and groundwater compositions, and is thus expected to be site-specific. Simulations of ore deposits that advance downstream with time demonstrate the formation of stronger 226Ra/238U disequilibria, as expected, in the downgradient side or nose of the ore, reflecting both younger mineralization ages and the presence of active uranium precipitation. Whether disequilibria are positive or negative with respect to secular equilibrium, however, depends on the 234U/238U activity ratio in the fluid from which uranium minerals precipitate. Smaller hydraulic conductivities are shown to generate a narrower range in 226Ra/238U activity ratios with distance, and may explain the occurrence of disequilibria in the limb ore that are less pronounced than those in the nose. Furthermore, the ability of α-recoil loss to decrease 226Ra/238U activity ratios at secular equilibrium may account for negative disequilibria in high grade ores. The South Tortkuduk uranium deposits (Kazakhstan) are subsequently used as a case study to identify the processes and parameters that may contribute to 226Ra/238U disequilibria at this site. Variations in multiple parameters, including clay contents, barite contents, and mineralization ages, are found to reproduce measured 226Ra/238U activity ratios in the roll-front ore. Prioritization of these parameters will necessitate field measurements targeting both groundwater fluids and the host rock. Results from this study will ultimately aid geologists in building appropriate hydrogeochemical data sets to more efficiently locate and exploit uranium ore deposits.  
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  ISSN 0375-6742 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ grozeva_reactive_2022 Serial 180  
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Author Jana, A.; Unni, A.; Ravuru, S.S.; Das, A.; Das, D.; Biswas, S.; Sheshadri, H.; De, S. url  openurl
  Title In-situ polymerization into the basal spacing of LDH for selective and enhanced uranium adsorption: A case study with real life uranium alkaline leach liquor Type Journal Article
  Year 2022 Publication Chemical Engineering Journal Abbreviated Journal  
  Volume 428 Issue Pages 131180  
  Keywords In-situ polymerization, Layered double hydroxide, Leach liquor, Uranium adsorption, Uranium recovery  
  Abstract Uranium is used as a fuel for nuclear power plant and can be extracted from different ores, mainly acidic (silicious ore) and alkaline (carbonate ore). Recovery of uranium through acid leaching from silicious ore is well established, whereas, alkaline leaching from carbonate ore is challenging due to the excessive salinity of leach liquor and high concentration of carbonate, bicarbonate and sulphate. Herein, two monomers, acrylic acid (AA) and N, N-methylene bisacrylamide (BAM), selective towards uranyl were intercalated in-situ into the interlayer, followed by their polymerization and cross-linking to form novel polymer intercalated hybrid layered double hydroxide (LDH). The LDH acts as a backbone to overcome coiling and swelling of polymer and anchors them as free-standing. Various parameters, like, the type of metal ions, monomer ratio (AA: BAM) and metal ion ratio (M2+:M3+), were studied to determine the optimum conditions for effective intercalation and polymerization of monomers. Magnesium aluminum (MgAl) LDH with a cross-linked polymer having a monomer ratio of 3:2 (AA: BAM) as intercalating species showed maximum efficiency of uranyl adsorption (1456 mg/g at 30 °C) with highest capacity so far. The distribution coefficient (Kd, l/mg) in the order of 105 suggested that the adsorbent was highly selective for uranyl in the presence of different cations, anions and humic acid. The adsorbent extracts uranium effectively and selectively from a real-life alkaline leach liquor with an efficiency of 96% at 5 g/l dose. Uranium can be recovered from the adsorbent in the form of sodium di-uranate using 2(M) NaOH and was reused for eight cycles.  
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  ISSN 1385-8947 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ jana_-situ_2022 Serial 209  
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Author Kazemi, A.; Esmaeilbeigi, M.; Sahebi, Z.; Ansari, A. url  openurl
  Title Health risk assessment of total chromium in the qanat as historical drinking water supplying system Type Journal Article
  Year 2022 Publication Science of The Total Environment Abbreviated Journal  
  Volume 807 Issue Pages 150795  
  Keywords Qanat, Total chromium, Hazard quotient, Non-carcinogenic risk, Risk assessment, Eastern Iran  
  Abstract This study investigated the health risk assessment of total chromium (CrT) in qanats of South Khorasan, Eastern Iran. For this, concentration of CrT in a total of 83 qanats were measured in summer 2020. Samples were initially tested in the field for temperature, pH, dissolved oxygen (DO), electrical conductivity (EC), and total dissolved solids (TDS). In the lab, collected samples were filtered and fixed with nitric acid (HNO3) for the detection of CrT using inductively coupled plasma mass spectrometry (ICP-MS). Hazard quotient (HQ) and carcinogenic risk assessments were considered to evaluate the risks of CrT to inhabitants. Results showed that concentration of CrT ranged from 1.79 to 1017.05 μg L-1, and a total of 25 stations illuminated CrT concentrations above the WHO standards (50 μg L-1). HQ demonstrated HQ < 1 for 90.37% of studied samples with negligible hazard, whereas 9.63% of stations illuminated HQ ≥ 1 meaning the presence of non-carcinogenic risk for water consumers. Carcinogenic risk (CR) exhibited CR > 1.00E-04 in 81.93% of qanats while 18.07% of stations had 1.00E-06 < CR < 1.00E-04 meaning no acceptable and acceptable CR for the studied qanats, respectively. Zoning map displayed that qanats in the south of South Khorasan possessed the highest HQ, but north regions showed the lowest ones. Together, CrT in qanats of South Khorasan is above the WHO limit, which results in a high risk of carcinogenicity for residents, and in turn, more efforts should be made to provide hygienic groundwater for consumers.  
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  ISSN 0048-9697 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ Kazemi2022150795 Serial 269  
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Author Khaneiki, M.L.; Al-Ghafri, A.S.; Klöve, B.; Haghighi, A.T. url  openurl
  Title Sustainability and virtual water: The lessons of history Type Journal Article
  Year 2022 Publication Geography and Sustainability Abbreviated Journal  
  Volume 3 Issue 4 Pages 358-365  
  Keywords Proto-industrialization, Water scarcity, Non-hydraulic polity, Virtual water, Political economy  
  Abstract This article aims to show that virtual water has historically been an adaptation strategy that enabled some arid regions to develop a prosperous economy without putting pressure on their scarce water resources. Virtual water is referred to as the total amount of water that is consumed to produce goods and services. As an example, in arid central Iran, the deficiency in agricultural revenues was offset by more investment in local industries that enjoyed a perennial capacity to employ more workers. The revenues of local industries weaned the population from irrigated agriculture, since most of their raw materials and also food stuff were imported from other regions, bringing a remarkable amount of virtual water. This virtual water not only sustained the region’s inhabitants, but also set the stage for a powerful polity in the face of a rapid population growth between the 13th and 15th centuries AD. The resultant surplus products entailed a vast and safe network of roads, provided by both entrepreneurs and government. Therefore, it became possible to import more feedstock such as cocoons from water-abundant regions and then export silk textiles with considerable value-added. This article concludes that a similar model of virtual water can remedy the ongoing water crisis in central Iran, where groundwater reserves are overexploited, and many rural and urban centers are teetering on the edge of socio-ecological collapse. History holds an urgent lesson on sustainability for our today’s policy that stubbornly peruses agriculture and other high-water-demand sectors in an arid region whose development has always been dependent on virtual water.  
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  ISSN 2666-6839 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ Khaneiki2022358 Serial 272  
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Author Kumar, V.; Setia, R.; Pandita, S.; Singh, S.; Mitran, T. url  openurl
  Title Assessment of U and As in groundwater of India: A meta-analysis Type Journal Article
  Year 2022 Publication Chemosphere Abbreviated Journal  
  Volume 303 Issue Pages 135199  
  Keywords Arsenic, Geology, Groundwater, Health risk, Soil texture, Uranium  
  Abstract More than 2.5 billion people depend upon groundwater worldwide for drinking, and giving quality water has become one of the great apprehensions of human culture. The contamination of Uranium (U) and Arsenic (As) in the groundwater of India is gaining global attention. The current review provides state-of-the-art groundwater contamination with U and As in different zones of India based on geology and soil texture. The average concentration of U in different zones of India was in the order: West Zone (41.07 μg/L) \textgreater North Zone (37.7 μg/L) \textgreater South Zone (13.5 μg/L)\textgreater Central Zone (7.4 μg/L) \textgreater East Zone (5.7 μg/L) \textgreaterSoutheast Zone (2.4 μg/L). The average concentration of As in groundwater of India is in the order: South Zone (369.7 μg/L)\textgreaterCentral Zone (260.4 μg/L)\textgreaterNorth Zone (67.7 μg/L)\textgreaterEast Zone (60.3 μg/L)\textgreaterNorth-east zone (9.78 μg/L)\textgreaterWest zone (4.14 μg/L). The highest concentration of U and As were found in quaternary sediments, but U in clay skeletal and As in loamy skeletal. Results of health risk assessment showed that the average health quotient of U in groundwater for children and adults was less than unity. In contrast, it was greater than unity for As posing a harmful impact on human health. This review provides the baseline data regarding the U and As contamination status in groundwater of India, and appropriate, effective control measures need to be taken to control this problem.  
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  ISSN 0045-6535 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ kumar_assessment_2022 Serial 161  
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Author Aldawsari, S.; Kampmann, R.; Harnisch, J.; Rohde, C. url  doi
openurl 
  Title Setting Time, Microstructure, and Durability Properties of Low Calcium Fly Ash/Slag Geopolymer: A Review Type Journal Article
  Year 2022 Publication Materials Abbreviated Journal  
  Volume 15 Issue 3 Pages  
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  Abstract Ordinary Portland cement (OPC) is known for its significant contribution to carbon dioxide emissions. Geopolymer has a lower footprint in terms of CO2 emissions and has been considered as an alternative for OPC. A well-developed understanding of the use of fly-ash-based and slag-based geopolymers as separate systems has been reached in the literature, specifically regarding their mechanical properties. However, the microstructural and durability of the combined system after slag addition introduces more interactive gels and complex microstructural formations. The microstructural changes of complex blended systems contribute to significant advances in the durability of fly ash/slag geopolymers. In the present review, the setting time, microstructural properties (gel phase development, permeability properties, shrinkage behavior), and durability (chloride resistance, sulfate attack, and carbonatation), as discussed literature, are studied and summarized to simplify and draw conclusions.  
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  ISSN 1996-1944 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ ma15030876 Serial 84  
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Author Eliades, M.; Bruggeman, A.; Djuma, H.; Christofi, C.; Kuells, C. url  doi
openurl 
  Title Quantifying Evapotranspiration and Drainage Losses in a Semi-Arid Nectarine (Prunus persica var. nucipersica) Field with a Dynamic Crop Coefficient (Kc) Derived from Leaf Area Index Measurements Type Journal Article
  Year 2022 Publication Water Abbreviated Journal  
  Volume 14 Issue 5 Pages  
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  Abstract Quantifying evapotranspiration and drainage losses is essential for improving irrigation efficiency. The FAO-56 is the most popular method for computing crop evapotranspiration. There is, however, a need for locally derived crop coefficients (Kc) with a high temporal resolution to reduce errors in the water balance. The aim of this paper is to introduce a dynamic Kc approach, based on Leaf Area Index (LAI) observations, for improving water balance computations. Soil moisture and meteorological data were collected in a terraced nectarine (Prunus persica var. nucipersica) orchard in Cyprus, from 22 March 2019 to 18 November 2021. The Kc was derived as a function of the canopy cover fraction (c), from biweekly in situ LAI measurements. The use of a dynamic Kc resulted in Kc estimates with a bias of 17 mm and a mean absolute error of 0.8 mm. Evapotranspiration (ET) ranged from 41% of the rainfall (P) and irrigation (I) in the wet year (2019) to 57% of P + I in the dry year (2021). Drainage losses from irrigation (DR_I) were 44% of the total irrigation. The irrigation efficiency in the nectarine field could be improved by reducing irrigation amounts and increasing the irrigation frequency. Future studies should focus on improving the dynamic Kc approach by linking LAI field observations with remote sensing observations and by adding ground cover observations.  
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  ISSN 2073-4441 ISBN Medium  
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  Notes Approved no  
  Call Number (up) THL @ christoph.kuells @ Marinos2022 Serial 82  
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