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Author Ren, Y.; Yang, X.; Hu, X.; Wei, J.; Tang, C. url  openurl
  Title Mineralogical and geochemical evidence for biogenic uranium mineralization in northern Songliao Basin, NE China Type Journal Article
  Year 2022 Publication Ore Geology Reviews Abbreviated Journal  
  Volume (up) 141 Issue Pages 104556  
  Keywords Bacterial sulfate reduction, In-situ S isotope of pyrite, Northern Songliao basin, Sandstone-type uranium deposit, Sifangtai Formation  
  Abstract The sandstone-hosted uranium mineralization areas in the Sanzhao Sag of the northern Songliao Basin have been newly identified. The target stratum is the Upper Cretaceous Sifangtai Formation and the uranium mineralization mainly occurs in the bottom of Sifangtai Formation, corresponding to channel sand bodies in meandering river system, characterized by medium to fine-grained sandstone. This study proposes the uranium metallogenic model through petrographic observation, whole rock geochemistry, mineralogical study of uranium occurrence form (SEM), organic matter rock–eval pyrolysis analysis (REP) and in-situ sulfur isotope determination of different generations of pyrite by LA-MC-ICP-MS. Compared with the sandstones collected in barren reduction and oxidization zones, the mineralized sandstones show obvious increase in the contents of TOC, total sulfur, Y and U. Petrographic observations indicate that organic matters are mainly inherited from land plants. REP data display that the organic matter (OM) disseminated in the sandstone has very low hydrogen index (HI) from around 0 to 21 mg HC/g TOC and varied oxygen index (OI) from 44 to 115 mg CO2/g TOC, corresponding to Type Ⅳ kerogen (degraded kerogen). There are two types of coffinite with different grain size, micro-particles (μm-sized) and large aggregates (generally up to 100 μm) respectively. The coffinite micro spherules exhibit short rod-like or worm-like morphology occurring in clay matrix and cell cavities in degradofusinite or around subidiomorphic-idiomorphic pyrite. The coarse-grained coffinite contains other mineral facies (e.g. pyrite, quartz) and some of large coffinite aggregates display thrombolite-type microbial structures. The irregular pyrite relict particles in coarse-grained colloidal coffinite have light sulfur isotope compositions characterized by δ34S values from –39.96‰ to –49.89‰. The δ34S values of colloidal pyrite in replacement of OM or of the sub-idiomorphic FeS2 cement filling in the cavities of OM range from –52.77‰ to –13.88‰. Some of sub-idiomorphic pyrite cement and idiomorphic crystal have the heavier signature from – 27.06‰ to + 14.23‰. The light sulfur isotope signature suggests that the sulfur originates from bacterial sulfate reduction (BSR). The OM replacement by pyrite and the highest OI values recorded by REP in uranium mineralized samples are lines of evidence of biodegradation. Bacteria use the organic matter as food source and produce isotopically light reduced sulfur species. Oxygenated uranium-bearing waters infiltrated through the denudated windows at Daqing placanticline into the porous reduced sandstones deposited in the Sanzhao Sag. Uranium was indirectly reduced by BSR-derived iron disulfides or directly reduced by sulfate-reducing bacteria.  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0169-1368 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ ren_mineralogical_2022 Serial 144  
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Author Romeo, N.; Mabry, J.; Hillegonds, D.; Kainz, G.; Jaklitsch, M.; Matsumoto, T. url  openurl
  Title Developments of a field gas extraction device and krypton purification system for groundwater radio-krypton dating at the IAEA Type Journal Article
  Year 2022 Publication Applied Radiation and Isotopes Abbreviated Journal  
  Volume (up) 189 Issue Pages 110450  
  Keywords  
  Abstract The long-lived radio-krypton isotope 81Kr (t1/2 = 2.29 × 105 yr) is an ideal tracer for old groundwater age dating in the range of 105–106 years which goes beyond the reach of radio-carbon (14C) age dating. Analytical breakthrough made over the last two decades in Atom Trap Trace Analysis (ATTA) has enabled the use of this isotope with extremely low abundance (81Kr/Kr = 6 × 10−13) to be used as a practical dating tool for very old groundwater. The International Atomic Energy Agency aims to provide this new isotope tool for better groundwater resource management of Member States and developed a field sampling device to collect dissolved gas samples from groundwater and a system to separate and purify trace amounts of krypton from the gas samples for the ATTA analysis. The design, setup and performances of our sampling and purification systems are described here. Our system can produce a high purity aliquot of about 5 μL of krypton from 5 L of air sample (recovery yield of >90%). The samples made by our system were confirmed to be acceptable for the ATTA analysis.  
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  Series Volume Series Issue Edition  
  ISSN 0969-8043 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Romeo2022110450 Serial 214  
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Author Grozeva, N.G.; Radwan, J.; Beaucaire, C.; Descostes, M. url  openurl
  Title Reactive transport modeling of U and Ra mobility in roll-front uranium deposits: Parameters influencing 226Ra/238U disequilibria Type Journal Article
  Year 2022 Publication Journal of Geochemical Exploration Abbreviated Journal  
  Volume (up) 236 Issue Pages 106961  
  Keywords Ra/U, Radioactive disequilibria, Radium, Reactive transport modeling, Roll-front uranium deposit  
  Abstract Uranium reserve estimates in ore deposits can be significantly impacted by 226Ra/238U disequilibria arising from the differential mobility of uranium and radium during groundwater transport. 1D reactive transport models were developed to investigate the long-term effects of retention processes (UO2(am) precipitation, U(VI) and Ra sorption on smectite, Ra co-precipitation with barite) on the repartitioning of 238U and 226Ra during formation of roll-front type deposits. Analytical solutions to radioactive decay chains were used in complement to examine the influence of geochemical parameters, including fluid 234U/238U activity ratios and α-recoil loss, on 226Ra/238U disequilibria in uranium ores. Model results demonstrate that smectite and barite can produce 226Ra/238U ratios \textgreater1 at low uranium contents and may explain 226Ra/238U disequilibria occurring in altered rock up- and downstream of roll-front deposits. The capacity of these phases to take up Ra and generate 226Ra/238U disequilibria depends on both mineral contents and groundwater compositions, and is thus expected to be site-specific. Simulations of ore deposits that advance downstream with time demonstrate the formation of stronger 226Ra/238U disequilibria, as expected, in the downgradient side or nose of the ore, reflecting both younger mineralization ages and the presence of active uranium precipitation. Whether disequilibria are positive or negative with respect to secular equilibrium, however, depends on the 234U/238U activity ratio in the fluid from which uranium minerals precipitate. Smaller hydraulic conductivities are shown to generate a narrower range in 226Ra/238U activity ratios with distance, and may explain the occurrence of disequilibria in the limb ore that are less pronounced than those in the nose. Furthermore, the ability of α-recoil loss to decrease 226Ra/238U activity ratios at secular equilibrium may account for negative disequilibria in high grade ores. The South Tortkuduk uranium deposits (Kazakhstan) are subsequently used as a case study to identify the processes and parameters that may contribute to 226Ra/238U disequilibria at this site. Variations in multiple parameters, including clay contents, barite contents, and mineralization ages, are found to reproduce measured 226Ra/238U activity ratios in the roll-front ore. Prioritization of these parameters will necessitate field measurements targeting both groundwater fluids and the host rock. Results from this study will ultimately aid geologists in building appropriate hydrogeochemical data sets to more efficiently locate and exploit uranium ore deposits.  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0375-6742 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ grozeva_reactive_2022 Serial 180  
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Author Paradis, C.J.; Hoss, K.N.; Meurer, C.E.; Hatami, J.L.; Dangelmayr, M.A.; Tigar, A.D.; Johnson, R.H. url  openurl
  Title Elucidating mobilization mechanisms of uranium during recharge of river water to contaminated groundwater Type Journal Article
  Year 2022 Publication Journal of Contaminant Hydrology Abbreviated Journal  
  Volume (up) 251 Issue Pages 104076  
  Keywords Desorption, Dissolution, Groundwater, Surface water, Tracer, Uranium  
  Abstract The recharge of stream water below the baseflow water table can mobilize groundwater contaminants, particularly redox-sensitive and sorptive metals such as uranium. However, in-situ tracer experiments that simulate the recharge of stream water to uranium-contaminated groundwater are lacking, thus limiting the understanding of the potential mechanisms that control the mobility of uranium at the field scale. In this study, a field tracer test was conducted by injecting 100 gal (379 l) of oxic river water into a nearby suboxic and uranium-contaminated aquifer. The traced river water was monitored for 18 days in the single injection well and in the twelve surrounding observation wells. Mobilization of uranium from the solid to the aqueous phase was not observed during the tracer test despite its pre-test presence being confirmed on the aquifer sediments from lab-based acid leaching. However, strong evidence of oxidative immobilization of iron and manganese was observed during the tracer test and suggested that immobile uranium was likely in its oxidized state as U(VI) on the aquifer sediments; these observations ruled out oxidation of U(IV) to U(VI) as a potential mobilization mechanism. Therefore, desorption of U(VI) appeared to be the predominant potential mobilization mechanism, yet it was clearly not solely dependent on concentration as evident when considering that uranium-poor river water (\textless0.015 mg/L) was recharged to uranium-rich groundwater (≈1 mg/L). It was possible that uranium desorption was limited by the relatively higher pH and lower alkalinity of the river water as compared to the groundwater; both factors favor immobilization. However, it was likely that the immobile uranium was associated with a mineral phase, as opposed to a sorbed phase, thus desorption may not have been possible. The results of this field tracer study successfully ruled out two common mobilization mechanisms of uranium: (1) oxidative dissolution and (2) concentration-dependent desorption and ruled in the importance of advection, dispersion, and the mineral phase of uranium.  
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  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0169-7722 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ paradis_elucidating_2022 Serial 135  
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Author Zhang, H.; Gao, J.; Xu, L.; Zhang, X. url  openurl
  Title Case studies of radioactivity of drilling mud for in situ leaching uranium mining in China Type Journal Article
  Year 2022 Publication Journal of Environmental Radioactivity Abbreviated Journal  
  Volume (up) 251-252 Issue Pages 106982  
  Keywords Drilling mud, Exemption management, In situ leaching, Radioactivity  
  Abstract The drilling mud from in situ leaching uranium mining is a type of low-radioactivity waste that contains natural nuclides and other harmful substances. In order to determine whether the drilling mud can meet the requirements of radioactive exemption management standards, field investigations and data simulations were conducted in this study. Two typical uranium mines were selected for onsite investigations. Drilling mud from different layers (i.e., the upper covering layer and ore-bearing layer) and from different stages (e.g., logging stage mud, drilling expansion stage mud, and mixed mud) was sampled. For each sample, the 238U and 226Ra concentrations of the solid components and the U and 226Ra concentrations of the supernatant were analyzed. The results revealed that the highest 238U and 226Ra concentrations of the solid components were 4122 Bq/kg and 4077 Bq/kg, while the 238U and 226Ra concentrations of the mixed drilling mud were all less than 300 Bq/kg. A radioactivity estimation model was established for scenario analysis. Exemption management screening lines of waste drilling mud, which can be used to classify and treat the drilling project according to the deposit’s grade and conditions, were proposed for in situ leaching drilling projects.  
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  Language Summary Language Original Title  
  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0265-931x ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ zhang_case_2022 Serial 191  
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Author Kumar, V.; Setia, R.; Pandita, S.; Singh, S.; Mitran, T. url  openurl
  Title Assessment of U and As in groundwater of India: A meta-analysis Type Journal Article
  Year 2022 Publication Chemosphere Abbreviated Journal  
  Volume (up) 303 Issue Pages 135199  
  Keywords Arsenic, Geology, Groundwater, Health risk, Soil texture, Uranium  
  Abstract More than 2.5 billion people depend upon groundwater worldwide for drinking, and giving quality water has become one of the great apprehensions of human culture. The contamination of Uranium (U) and Arsenic (As) in the groundwater of India is gaining global attention. The current review provides state-of-the-art groundwater contamination with U and As in different zones of India based on geology and soil texture. The average concentration of U in different zones of India was in the order: West Zone (41.07 μg/L) \textgreater North Zone (37.7 μg/L) \textgreater South Zone (13.5 μg/L)\textgreater Central Zone (7.4 μg/L) \textgreater East Zone (5.7 μg/L) \textgreaterSoutheast Zone (2.4 μg/L). The average concentration of As in groundwater of India is in the order: South Zone (369.7 μg/L)\textgreaterCentral Zone (260.4 μg/L)\textgreaterNorth Zone (67.7 μg/L)\textgreaterEast Zone (60.3 μg/L)\textgreaterNorth-east zone (9.78 μg/L)\textgreaterWest zone (4.14 μg/L). The highest concentration of U and As were found in quaternary sediments, but U in clay skeletal and As in loamy skeletal. Results of health risk assessment showed that the average health quotient of U in groundwater for children and adults was less than unity. In contrast, it was greater than unity for As posing a harmful impact on human health. This review provides the baseline data regarding the U and As contamination status in groundwater of India, and appropriate, effective control measures need to be taken to control this problem.  
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  Series Editor Series Title Abbreviated Series Title  
  Series Volume Series Issue Edition  
  ISSN 0045-6535 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ kumar_assessment_2022 Serial 161  
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Author Prusty, S.; Somu, P.; Sahoo, J.K.; Panda, D.; Sahoo, S.K.; Sahoo, S.K.; Lee, Y.R.; Jarin, T.; Sundar, L.S.; Rao, K.S. url  openurl
  Title Adsorptive sequestration of noxious uranium (VI) from water resources: A comprehensive review Type Journal Article
  Year 2022 Publication Chemosphere Abbreviated Journal  
  Volume (up) 308 Issue Pages 136278  
  Keywords Adsorbents, Adsorption, Techniques, Uranium, Wastewater  
  Abstract Groundwater is usually utilized as a drinking water asset everywhere. Therefore, groundwater defilement by poisonous radioactive metals such as uranium (VI) is a major concern due to the increase in nuclear power plants as well as their by-products which are released into the watercourses. Waste Uranium (VI) can be regarded as a by-product of the enrichment method used to produce atomic energy, and the hazard associated with this is due to the uranium radioactivity causing toxicity. To manage these confronts, there are so many techniques that have been introduced but among those adsorptions is recognized as a straightforward, successful, and monetary innovation, which has gotten major interest nowadays, despite specific drawbacks regarding operational as well as functional applications. This review summarizes the various adsorbents such as Bio-adsorbent/green materials, metal oxide-based adsorbent, polymer based adsorbent, graphene oxide based adsorbent, and magnetic nanomaterials and discuss their synthesis methods. Furthermore, this paper emphasis on adsorption process by various adsorbents or modified forms under different physicochemical conditions. In addition to this adsorption mechanism of uranium (VI) onto different adsorbent is studied in this article. Finally, from the literature reviewed conclusion have been drawn and also proposed few future research suggestions.  
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  Series Volume Series Issue Edition  
  ISSN 0045-6535 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ prusty_adsorptive_2022 Serial 131  
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Author Emparanza, A.R.; Kampmann, R.; Caso, F.D.; Morales, C.; Nanni, A. url  openurl
  Title Durability assessment of GFRP rebars in marine environments Type Journal Article
  Year 2022 Publication Construction and Building Materials Abbreviated Journal  
  Volume (up) 329 Issue Pages 127028  
  Keywords Composite FRP rebar, Durability, Service life, Marine structures, Reinforced concrete  
  Abstract Technologies developed over the last two decades have facilitated the use of glass fiber reinforced polymer (GFRP) bars as internal reinforcement for concrete structures, specially in coastal environments, mainly due to their corrosion resistance. To-date, most durability studies have focused on a single mechanical parameter (tensile strength) and a single aging environment (exposure to high alkalinity). However, knowledge gaps exists in understanding how other mechanical parameters and relevant conditioning environments may affect the durability of GFRP bars. To this end, this study assesses the durability for different physio-mechanical properties of GFRP rebars, post exposure to accelerated conditioning in seawater. Six different GFRP rebar types were submerged in seawater tanks, at various temperatures (23°C, 40°C and 60°C) for different time periods (60, 120, 210 and 365 days). In total six different physio-mechanical properties were assessed, including: tensile strength, E-modulus, transverse and horizontal shear strength, micro-structural composition and lastly, bond strength. It was inferred that rebars with high moisture absorption resulted in poor durability, in that it affected mainly the tensile strength. Based on the Arrhenius model, at 23°C all the rebars that met the acceptance criteria by ASTM D7957 are expected to retain 85% of the tensile strength capacity.  
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  Series Volume Series Issue Edition  
  ISSN 0950-0618 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Ruizemparanza2022127028 Serial 83  
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Author Jana, A.; Unni, A.; Ravuru, S.S.; Das, A.; Das, D.; Biswas, S.; Sheshadri, H.; De, S. url  openurl
  Title In-situ polymerization into the basal spacing of LDH for selective and enhanced uranium adsorption: A case study with real life uranium alkaline leach liquor Type Journal Article
  Year 2022 Publication Chemical Engineering Journal Abbreviated Journal  
  Volume (up) 428 Issue Pages 131180  
  Keywords In-situ polymerization, Layered double hydroxide, Leach liquor, Uranium adsorption, Uranium recovery  
  Abstract Uranium is used as a fuel for nuclear power plant and can be extracted from different ores, mainly acidic (silicious ore) and alkaline (carbonate ore). Recovery of uranium through acid leaching from silicious ore is well established, whereas, alkaline leaching from carbonate ore is challenging due to the excessive salinity of leach liquor and high concentration of carbonate, bicarbonate and sulphate. Herein, two monomers, acrylic acid (AA) and N, N-methylene bisacrylamide (BAM), selective towards uranyl were intercalated in-situ into the interlayer, followed by their polymerization and cross-linking to form novel polymer intercalated hybrid layered double hydroxide (LDH). The LDH acts as a backbone to overcome coiling and swelling of polymer and anchors them as free-standing. Various parameters, like, the type of metal ions, monomer ratio (AA: BAM) and metal ion ratio (M2+:M3+), were studied to determine the optimum conditions for effective intercalation and polymerization of monomers. Magnesium aluminum (MgAl) LDH with a cross-linked polymer having a monomer ratio of 3:2 (AA: BAM) as intercalating species showed maximum efficiency of uranyl adsorption (1456 mg/g at 30 °C) with highest capacity so far. The distribution coefficient (Kd, l/mg) in the order of 105 suggested that the adsorbent was highly selective for uranyl in the presence of different cations, anions and humic acid. The adsorbent extracts uranium effectively and selectively from a real-life alkaline leach liquor with an efficiency of 96% at 5 g/l dose. Uranium can be recovered from the adsorbent in the form of sodium di-uranate using 2(M) NaOH and was reused for eight cycles.  
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  Series Volume Series Issue Edition  
  ISSN 1385-8947 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ jana_-situ_2022 Serial 209  
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Author Sedghi, M.M.; Zhan, H. url  openurl
  Title On the discharge variation of a qanat in an alluvial fan aquifer Type Journal Article
  Year 2022 Publication Journal of Hydrology Abbreviated Journal  
  Volume (up) 610 Issue Pages 127922  
  Keywords Analytical solution, Wedge-shaped aquifer, Image well, Areal recharge  
  Abstract Qanat is a passive (unpumped) horizontal well (or a slant well with a very mild inclined angle) that is capable of extracting water from aquifers by gravity. Many qanats are constructed along the radius of the alluvial fan wedge-shaped aquifers. Analytical modeling of such a qanat-aquifer system provides great benefit for quickly screening different designs of qanats and accessing the performance of qanat discharge in the field. The previous analytical modeling of discharge of qanats, however, did not consider the wedge-shaped aquifers. Thus, the goal of this research is to obtain semi-analytical solutions of discharge variations of qanats in alluvial fan aquifers with nearby pumping wells, subjected to areal recharges due to rainfall. The uniform head boundary is considered inside the qanat (because of its enormous permeability in respect to the background aquifer). The influences of the aquifer lateral boundaries on discharge of qanat and its sensitivity to hydraulic and geometric parameters are explored. The influences of the lateral boundaries on the discharge of qanat due to areal recharge and nearby pumping wells discharge are also explored. The results of this study can be utilized for multiple purposes: 1) to predict the discharge of qanat in an alluvial fan aquifer and explore the influences of the areal recharge and nearby pumping well discharge; 2) to estimate the hydraulic parameters of the alluvial fan aquifer depleted by a qanat; 3) to determine the location of the nearby pumping well to minimize its influences on the discharge of a qanat; 4) to calculate the water budgets of aquifers depleted by qanats and pumping wells and replenished by areal recharge among other applications. This paper is an extension to the work presented by Sedghi and Zhan (2020) (which concerns an infinite unconfined aquifer) for an unconfined alluvial fan aquifer setting.  
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  Series Volume Series Issue Edition  
  ISSN 0022-1694 ISBN Medium  
  Area Expedition Conference  
  Notes Approved no  
  Call Number THL @ christoph.kuells @ Sedghi2022127922 Serial 267  
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