Abstract: The long-lived radio-krypton isotope 81Kr (t1/2 = 2.29 × 105 yr) is an ideal tracer for old groundwater age dating in the range of 105–106 years which goes beyond the reach of radio-carbon (14C) age dating. Analytical breakthrough made over the last two decades in Atom Trap Trace Analysis (ATTA) has enabled the use of this isotope with extremely low abundance (81Kr/Kr = 6 × 10−13) to be used as a practical dating tool for very old groundwater. The International Atomic Energy Agency aims to provide this new isotope tool for better groundwater resource management of Member States and developed a field sampling device to collect dissolved gas samples from groundwater and a system to separate and purify trace amounts of krypton from the gas samples for the ATTA analysis. The design, setup and performances of our sampling and purification systems are described here. Our system can produce a high purity aliquot of about 5 μL of krypton from 5 L of air sample (recovery yield of >90%). The samples made by our system were confirmed to be acceptable for the ATTA analysis.

Abstract: Despite the attention currently given to the potential environmental benefits of large-scale forest planting, there is a shortage of clear observational evidence regarding the effects on river flows, and what there is has often been contradictory or inconclusive. This paper presents three independently conducted paired-catchment forestry studies covering 66 station-years of flow measurements in the UK and Ireland. In each case coniferous evergreen trees were removed from one catchment with minimal soil disturbance while the adjoining control catchment was left unchanged. Trees were removed from 20% – 90% of the three experimental basins. Following woodland removal there was an increase in dry weather baseflow at all sites. Baseflows increased by about 8% after tree removal from a quarter of the Hore basin and by 41% for the near-total cut at Howan. But the changes were more complex for peak flows. Tree harvesting increased the smallest and most frequent peak storm flows, indicating that afforestation would lead to the suppression of such events. This was however restricted to events well below the mean annual flood, indicating that the impact of forests upon the largest and most damaging floods is likely to be limited. Whilst a forest cover can be effective in mitigating small and frequent stormflows it should never be assumed to provide protection against major flood events.

Abstract: With its arid and semi-arid climate, Iran claims about one-third of the world’s average annual precipitation. Accordingly, the present study investigated whether an effective water resources management (WRM) strategy (both groundwater and reservoir resources) could reduce groundwater drawdown while simultaneously providing secure enough water for preservation of agricultural activities and rural settlements. For this purpose, a comprehensive system dynamics (SD) model incorporating reservoir, surface-water, and groundwater resources was developed. Then, the model was implemented for the Nesa plain in Bam County, Iran, as an example. In this plain, the construction of a dam to supply drinking water to the cities of Bam and the Bam Industrial Zone had devastated the environment and human communities in the downstream areas, leading to the depopulation of as many as 104 villages in the Bam region. The results of the SD model revealed that the artificial recharge of the plain groundwater aquifer along with the management of the operation of the wells and increasing productivity would be very effective. In order to estimate future precipitation data, the SDSM statistical exponential microscale model was used to microscale the large CanESM2 scale model under two scenarios of RCP4.5 and RCP8.5. The continuation of the current trend of the groundwater resources in the plain during the next 20 years will also cause a drop in water level of 8.3 m compared with the existing situation and a reduction of 41 m compared with the long-term average of 1980. Based on this modeling effort, upon releasing 60% of river flow, surplus to downstream demand, for recharging aquifer through artificial recharge projects, the rate of water table fall will decline significantly over a 20-year period and the amount of negative aquifer water balance would most likely improve from 65.5 to 35.17 million cubic meters annually.

Abstract: This study investigated the health risk assessment of total chromium (CrT) in qanats of South Khorasan, Eastern Iran. For this, concentration of CrT in a total of 83 qanats were measured in summer 2020. Samples were initially tested in the field for temperature, pH, dissolved oxygen (DO), electrical conductivity (EC), and total dissolved solids (TDS). In the lab, collected samples were filtered and fixed with nitric acid (HNO3) for the detection of CrT using inductively coupled plasma mass spectrometry (ICP-MS). Hazard quotient (HQ) and carcinogenic risk assessments were considered to evaluate the risks of CrT to inhabitants. Results showed that concentration of CrT ranged from 1.79 to 1017.05 μg L-1, and a total of 25 stations illuminated CrT concentrations above the WHO standards (50 μg L-1). HQ demonstrated HQ < 1 for 90.37% of studied samples with negligible hazard, whereas 9.63% of stations illuminated HQ ≥ 1 meaning the presence of non-carcinogenic risk for water consumers. Carcinogenic risk (CR) exhibited CR > 1.00E-04 in 81.93% of qanats while 18.07% of stations had 1.00E-06 < CR < 1.00E-04 meaning no acceptable and acceptable CR for the studied qanats, respectively. Zoning map displayed that qanats in the south of South Khorasan possessed the highest HQ, but north regions showed the lowest ones. Together, CrT in qanats of South Khorasan is above the WHO limit, which results in a high risk of carcinogenicity for residents, and in turn, more efforts should be made to provide hygienic groundwater for consumers.