Abstract: Ordinary Portland cement (OPC) is known for its significant contribution to carbon dioxide emissions. Geopolymer has a lower footprint in terms of CO2 emissions and has been considered as an alternative for OPC. A well-developed understanding of the use of fly-ash-based and slag-based geopolymers as separate systems has been reached in the literature, specifically regarding their mechanical properties. However, the microstructural and durability of the combined system after slag addition introduces more interactive gels and complex microstructural formations. The microstructural changes of complex blended systems contribute to significant advances in the durability of fly ash/slag geopolymers. In the present review, the setting time, microstructural properties (gel phase development, permeability properties, shrinkage behavior), and durability (chloride resistance, sulfate attack, and carbonatation), as discussed literature, are studied and summarized to simplify and draw conclusions.

Abstract: Quantifying evapotranspiration and drainage losses is essential for improving irrigation efficiency. The FAO-56 is the most popular method for computing crop evapotranspiration. There is, however, a need for locally derived crop coefficients (Kc) with a high temporal resolution to reduce errors in the water balance. The aim of this paper is to introduce a dynamic Kc approach, based on Leaf Area Index (LAI) observations, for improving water balance computations. Soil moisture and meteorological data were collected in a terraced nectarine (Prunus persica var. nucipersica) orchard in Cyprus, from 22 March 2019 to 18 November 2021. The Kc was derived as a function of the canopy cover fraction (c), from biweekly in situ LAI measurements. The use of a dynamic Kc resulted in Kc estimates with a bias of 17 mm and a mean absolute error of 0.8 mm. Evapotranspiration (ET) ranged from 41% of the rainfall (P) and irrigation (I) in the wet year (2019) to 57% of P + I in the dry year (2021). Drainage losses from irrigation (DR_I) were 44% of the total irrigation. The irrigation efficiency in the nectarine field could be improved by reducing irrigation amounts and increasing the irrigation frequency. Future studies should focus on improving the dynamic Kc approach by linking LAI field observations with remote sensing observations and by adding ground cover observations.

Abstract: Qanat is a passive (unpumped) horizontal well (or a slant well with a very mild inclined angle) that is capable of extracting water from aquifers by gravity. Many qanats are constructed along the radius of the alluvial fan wedge-shaped aquifers. Analytical modeling of such a qanat-aquifer system provides great benefit for quickly screening different designs of qanats and accessing the performance of qanat discharge in the field. The previous analytical modeling of discharge of qanats, however, did not consider the wedge-shaped aquifers. Thus, the goal of this research is to obtain semi-analytical solutions of discharge variations of qanats in alluvial fan aquifers with nearby pumping wells, subjected to areal recharges due to rainfall. The uniform head boundary is considered inside the qanat (because of its enormous permeability in respect to the background aquifer). The influences of the aquifer lateral boundaries on discharge of qanat and its sensitivity to hydraulic and geometric parameters are explored. The influences of the lateral boundaries on the discharge of qanat due to areal recharge and nearby pumping wells discharge are also explored. The results of this study can be utilized for multiple purposes: 1) to predict the discharge of qanat in an alluvial fan aquifer and explore the influences of the areal recharge and nearby pumping well discharge; 2) to estimate the hydraulic parameters of the alluvial fan aquifer depleted by a qanat; 3) to determine the location of the nearby pumping well to minimize its influences on the discharge of a qanat; 4) to calculate the water budgets of aquifers depleted by qanats and pumping wells and replenished by areal recharge among other applications. This paper is an extension to the work presented by Sedghi and Zhan (2020) (which concerns an infinite unconfined aquifer) for an unconfined alluvial fan aquifer setting.

Abstract: This study combines historical records of 14C and 3H in the atmosphere and soil with renewal rate and groundwater lumped parameter models to predict the abundance of 14C and 3H in groundwater over time. 624 groundwater samples from numerous studies, over four decades (1978–2019), in South Africa, Namibia, Botswana and Mozambique were collated to compare with predicted groundwater activities of 14C and 3H within the South African Development Community (SADC) region. Spatial datasets of carbonate bearing lithology, C3/C4 vegetation, summer/winter rainfall and coastal proximity were used to apply corrections to 14C and 3H data. Corrected values of 14C and 3H were compared with the theoretical abundance of these tracers, derived from the lumped parameter models, to estimate the general mean residence times and presence of groundwater mixing between modern recharge and older groundwaters. This study found that corrected values produced varying mean residence times derived from 14C ages (∼500–28500 years) and a wide range of potentially mixed waters within each aquifer system (0–100 % of tested wells) across the study area. The largest proportions of mixed groundwater, as well as the youngest mean residence times, were found in alluvial and primary fractured rock aquifers (e.g., western coast of South Africa and southern Mozambique). The smallest proportions of mixed groundwater were predicted in deep confined clay-rich aquifers as well as layered coal bearing carbonate sequences (e.g., Orapa, Malwewe and Serowe, Botswana). Insights into the proportions of mixed groundwater and mean residence times can help assess hydrological resilience on a regional scale. Such information is pertinent in promoting socio-economic development and increased water/food security in the SADC region. By understanding the resilience of groundwater resources, robust and informed strategies for water equality and GDP growth in the SADC region can be envisioned and implemented.

Abstract: More than 2.5 billion people depend upon groundwater worldwide for drinking, and giving quality water has become one of the great apprehensions of human culture. The contamination of Uranium (U) and Arsenic (As) in the groundwater of India is gaining global attention. The current review provides state-of-the-art groundwater contamination with U and As in different zones of India based on geology and soil texture. The average concentration of U in different zones of India was in the order: West Zone (41.07 μg/L) \textgreater North Zone (37.7 μg/L) \textgreater South Zone (13.5 μg/L)\textgreater Central Zone (7.4 μg/L) \textgreater East Zone (5.7 μg/L) \textgreaterSoutheast Zone (2.4 μg/L). The average concentration of As in groundwater of India is in the order: South Zone (369.7 μg/L)\textgreaterCentral Zone (260.4 μg/L)\textgreaterNorth Zone (67.7 μg/L)\textgreaterEast Zone (60.3 μg/L)\textgreaterNorth-east zone (9.78 μg/L)\textgreaterWest zone (4.14 μg/L). The highest concentration of U and As were found in quaternary sediments, but U in clay skeletal and As in loamy skeletal. Results of health risk assessment showed that the average health quotient of U in groundwater for children and adults was less than unity. In contrast, it was greater than unity for As posing a harmful impact on human health. This review provides the baseline data regarding the U and As contamination status in groundwater of India, and appropriate, effective control measures need to be taken to control this problem.