TY - JOUR AU - Vogel, J. C. AU - Talma, A. S. AU - Heaton, T. H. E. AU - Kronfeld, J. PY - 1999// TI - Evaluating the rate of migration of an uranium deposition front within the Uitenhage Aquifer JO - Journal of Geochemical Exploration SP - 269 EP - 276 VL - 66 IS - 1 KW - redox changes in aquifer KW - sandstone-type uranium deposit KW - South Africa KW - uranium series N2 - The solubility of uranium in groundwater is very sensitive to changes in redox conditions. Many secondary (sandstone-type) uranium deposits have been formed when soluble U has precipitated after encountering reducing conditions in the subsurface. In the groundwater of the Uitenhage Aquifer (Cape Province, South Africa), 238U-series isotopes were used to assist in studying the history of the reducing barrier. Uranium isotopes were used to determine the present position of the barrier. Radium and radon were used to evaluate the path of migration that the front of the oxygen depletion zone has taken over the past 105 years. During this time the reducing barrier has moved, leaving in its wake a trail of U in various stages of secular equilibrium with its daughter 230Th. The 226Ra daughter of 230Th is not very mobile. Its growth upon the aquifer wall is reflected in the Rn content of the water. This in turn, due to the relatively great age of the water, indicates the extent of the 230Th ingrowth (from precipitated U) that took place before the barrier migrated. SN - 0375-6742 UR - https://www.sciencedirect.com/science/article/pii/S037567429900031X N1 - exported from refbase (http://www.uhydro.de/base/show.php?record=126), last updated on Fri, 26 Jan 2024 13:19:04 +0100 ID - Vogel_etal1999 ER -