Abstract: The concentration of the bioavailable uranium fraction (Ubio) at the European scale was deduced by geochemical modelling considering several definitions found in the literature and the FOREGS European stream waters geochemical atlas dataset to produce a Ubio baseline. A sensitivity analysis was performed using three thermodynamic databases. We also investigated the link between total dissolved uranium (Uaq) concentrations, speciation and global stream water chemistry on the one hand, and the lithology and ages of the surrounding rocks on the other. The more U-enriched the stream sediments or rock type contexts are, which tends to be the case with rocks containing silicates (4.1 mg/kg), the less U-concentrated the stream waters are (0.15 μg/L). Sedimentary rocks lead to slightly higher Uaq concentrations (0.34 μg/L) even if the concentration in sediment (Used) is relatively low (1.6 mg/kg). This trend is reversed for Ubio, with higher concentrations in a crystalline context. The mean estimated Ubio value ranges from 1.5.10−3 to 65.3 ng/L and can fluctuate by 3 orders of magnitude depending on the considered definition as opposed to by 2 orders of magnitude accountable to differences between thermodynamic databases. The classification of the water in relation to the two surrounding rock lithologies makes it possible to reduce the mean variability for the Ubio concentrations. Irrespective of the definition of Ubio considered, in 59% of cases the Ubio fraction represents less than 1% of Uaq. Several threshold values relating to Ubio were proposed, assuming knowledge only of the aqueous concentrations of the major elements and Uaq.

Abstract: In urban environments there is a severe reduction of infiltration and groundwater recharge due to the existence of large impervious areas. During rain events, large volumes of water that could have recharged groundwater and surface water bodies are diverted into the municipal drainage system and lost from the freshwater storage. Moreover, extreme rain events impose high peak flows and large runoff volumes, which increase the risk of urban floods. Recent studies have suggested the use of rainwater harvesting for groundwater recharge, as a plausible solution for these challenges in dense urban environments. While the benefits of this approach are well understood, research on its practical, engineering, and hydrological aspects is relatively limited. The objective of the present study was to examine the use of infiltration wells for groundwater recharge with harvested rainwater collected from building rooftops under Mediterranean climate conditions. Two types of wells with similar hydraulic and technical properties were examined: a well that reaches the groundwater (wet well); and a well that discharges the harvested water into the unsaturated zone (dry well). Infiltration capacities of the wells were compared in controlled experiments conducted during summer months, and in operational recharge of harvested rainwater, during winter. Both dry and wet wells were found to be suitable for purposes of groundwater recharge with rooftop-harvested rainwater. Infiltration capacity of the wet well was about seven times greater than the infiltration capacity of the dry well. While the infiltration capacity of the wet well was constant throughout the entire length of the study (∼10 m3/h/m), the dry well infiltration capacity improved during winter (from 0.5 m3/h/m to 1.5 m3/h/m), a result of development of the dry well with time. Considering Tel-Aviv, Israel, as a case study for a dense modern city in a Mediterranean climate, it is demonstrated herein that the use of infiltration wells may reduce urban drainage by ∼40 %.

Abstract: Combined large-scale rainwater harvesting (RWH) and flood mitigation systems are promising as a sustainable water management strategy in urban areas. These are multi-purpose infrastructure that not only provide a secondary, localised water resource, but can also reduce discharge and hence loads on any downstream wastewater networks if these are integrated into the wider water network. However, the performance of these systems is dependent on the specific design used for its local catchment which can vary significantly between different implementations. A multitude of design strategies exist, however there is no universally accepted standard framework. To tackle these issues, this paper presents a two-player optimisation framework which utilises a stochastic design optimisation model and a competing, high-intensity rainfall design model to optimise passively-operated RWH systems. A customisable tool set is provided, under which optimisation models specific to a given catchment can be built quickly. This reduces the barriers to implementing computationally complex sizing strategies and encouraging more resource-efficient systems to be built. The framework was applied to a densely populated high-rise residential estate, eliminating overflow events from historical rainfall. The optimised configuration resulted in a 32% increase in harvested water yield, but its ability to meet irrigation demands was limited by the operational levels of the treatment pump. Hence, with the inclusion of operational levels in the optimisation model, the framework can provide an efficient large-scale RWH system that is capable of simultaneously meeting water demands and reducing stresses within and beyond its local catchment.